Coordinatively unsaturated metal sites (open metal sites) in metal–organic frameworks: design and applications

Potential Flue Gas Impurities in Carbon Dioxide Streams Separated from Coal-Fired Power Plants

Lee, J., Keener, T. C., & Yang, Y. J. (2009) · Journal of the Air & Waste Management Association · doi:10.3155/1047-3289.59.6.725 · Cited by 132

Synthesis of quinolines via Friedländer reaction catalyzed by CuBTC metal–organic-framework

Pérez‐Mayoral, E., Musilová, Z., Gil, B., et al. (2012) · Dalton Transactions · doi:10.1039/c2dt11978a · Cited by 132

Nitric Oxide Chemisorption in a Postsynthetically Modified Metal−Organic Framework

Ingleson, M. J., Heck, R., Gould, J. A., & Rosseinsky, M. J. (2009) · Inorganic Chemistry · doi:10.1021/ic9015977 · Cited by 128

Hydrogen Storage and Selective, Reversible O2 Adsorption in a Metal–Organic Framework with Open Chromium(II) Sites

Bloch, E. D., Queen, W. L., Hudson, M. R., Mason, J. A., Xiao, D. J., Murray, L. J., Flacau, R., Brown, C. M., & Long, J. R. (2016) · Angewandte Chemie International Edition · doi:10.1002/anie.201602950 · Cited by 125

Organophophorous Ester Degradation by Chromium(III) Terephthalate Metal–Organic Framework (MIL-101) Chelated to N,N-Dimethylaminopyridine and Related Aminopyridines

Wang, S., Bromberg, L. E., Schreuder‐Gibson, H. L., & Hatton, T. A. (2013) · ACS Applied Materials & Interfaces · doi:10.1021/am302359b · Cited by 121

Strategies to enhance CO 2 capture and separation based on engineering absorbent materials

Lü, X., Jin, D., Wei, S., Wang, Z., An, C., & Guo, W. (2015) · Journal of Materials Chemistry A · doi:10.1039/c4ta06829g · Cited by 121

Improving Predictions of Gas Adsorption in Metal–Organic Frameworks with Coordinatively Unsaturated Metal Sites: Model Potentials, ab initio Parameterization, and GCMC Simulations

Chen, L., Morrison, C. A., & Düren, T. (2012) · The Journal of Physical Chemistry C · doi:10.1021/jp3062527 · Cited by 119

Force Field Development from Periodic Density Functional Theory Calculations for Gas Separation Applications Using Metal–Organic Frameworks

Mercado, R., Vlaisavljevich, B., Lin, L., Lee, K., Lee, Y., Mason, J. A., Xiao, D. J., Gonzalez, M. I., Kapelewski, M. T., Neaton, J. B., et al. (2016) · The Journal of Physical Chemistry C · doi:10.1021/acs.jpcc.6b03393 · Cited by 119

Photothermal Activation of Metal–Organic Frameworks Using a UV–Vis Light Source

Espín, J., Garzón‐Tovar, L., Carné‐Sánchez, A., Imaz, I., & Maspoch, D. (2018) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.8b00557 · Cited by 119

Metal–organic frameworks as high-potential adsorbents for liquid-phase separations of olefins, alkylnaphthalenes and dichlorobenzenes

Alaerts, L., Maes, M., van der Veen, M. A., Jacobs, P. A., & Vos, D. E. D. (2009) · Physical Chemistry Chemical Physics · doi:10.1039/b823233d · Cited by 117

Ab Initio Derived Force Fields for Predicting CO2 Adsorption and Accessibility of Metal Sites in the Metal–Organic Frameworks M-MOF-74 (M = Mn, Co, Ni, Cu)

Haldoupis, E., Borycz, J., Shi, H., Vogiatzis, K. D., Bai, P., Queen, W. L., Gagliardi, L., & Siepmann, J. I. (2015) · The Journal of Physical Chemistry C · doi:10.1021/acs.jpcc.5b03700 · Cited by 114

Understanding the Adsorption Mechanism of C2H2, CO2, and CH4 in Isostructural Metal–Organic Frameworks with Coordinatively Unsaturated Metal Sites

Hou, X., He, P., Li, H., & Wang, X. (2013) · The Journal of Physical Chemistry C · doi:10.1021/jp310517r · Cited by 112

Methane storage in porous metal−organic frameworks: current records and future perspectives

Zhou, W. (2010) · The Chemical Record · doi:10.1002/tcr.201000004 · Cited by 109

Optimization of membrane unit for removing carbon dioxide from natural gas

Datta, A. K., & Sen, P. K. (2006) · Journal of Membrane Science · doi:10.1016/j.memsci.2006.06.043 · Cited by 108

Trace Flue Gas Contaminants Poison Coordinatively Unsaturated Metal–Organic Frameworks: Implications for CO 2 Adsorption and Separation

Yu, K., Kiesling, K., & Schmidt, J. R. (2012) · The Journal of Physical Chemistry C · doi:10.1021/jp307894e · Cited by 108

Post-synthesis functionalization of MIL-101 using diethylenetriamine: a study on adsorption and catalysis

Kim, S., Yang, S.-T., Kim, J., Park, J. E., & Ahn, W. (2012) · CrystEngComm · doi:10.1039/c2ce06608d · Cited by 107

Structural characterization of framework–gas interactions in the metal–organic framework Co 2 (dobdc) by in situ single-crystal X-ray diffraction

Gonzalez, M. I., Mason, J. A., Bloch, E. D., Teat, S. J., Gagnon, K. J., Morrison, G. Y., Queen, W. L., & Long, J. R. (2017) · Chemical Science · doi:10.1039/c7sc00449d · Cited by 107

Homodiamine-functionalized metal–organic frameworks with a MOF-74-type extended structure for superior selectivity of CO 2 over N 2

Yeon, J. S., Lee, W. R., Kim, N. W., Jo, H., Lee, H., Song, J. H., Lim, K. S., Kang, D. W., Seo, J. G., Moon, D., et al. (2015) · Journal of Materials Chemistry A · doi:10.1039/c5ta02357b · Cited by 104

Well-studied Cu–BTC still serves surprises: evidence for facile Cu2+/Cu+ interchange

Szanyi, J., Daturi, M., Clet, G., Baer, D. R., & Peden, C. H. F. (2012) · Physical Chemistry Chemical Physics · doi:10.1039/c2cp23708c · Cited by 104

An Accurate and Transferable Intermolecular Diatomic Hydrogen Potential for Condensed Phase Simulation

Belof, J. L., Stern, A. C., & Space, B. (2008) · Journal of Chemical Theory and Computation · doi:10.1021/ct800155q · Cited by 104

Adsorptive Removal of Artificial Sweeteners from Water Using Metal–Organic Frameworks Functionalized with Urea or Melamine

Seo, P. W., Khan, N. A., Hasan, Z., & Jhung, S. H. (2016) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.6b11115 · Cited by 104

CO2 Capture in Dry and Wet Conditions in UTSA-16 Metal–Organic Framework

Masala, A., Vitillo, J. G., Mondino, G., Grande, C. A., Blom, R., Manzoli, M., Marshall, M., & Bordiga, S. (2016) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.6b13216 · Cited by 101

Highly Selective and Reversible Sulfur Dioxide Adsorption on a Microporous Metal–Organic Framework via Polar Sites

Zhang, Y., Zhang, P., Yu, W., Zhang, J., Huang, J., Wang, J., Xu, M., Deng, Q., Zeng, Z., & Deng, S. (2019) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.9b01423 · Cited by 101

Computational approaches to study adsorption in MOFs with unsaturated metal sites

Fischer, M., Gomes, J. R. B., & Jorge, M. (2014) · Molecular Simulation · doi:10.1080/08927022.2013.829228 · Cited by 100

Accurate Prediction of Methane Adsorption in a Metal–Organic Framework with Unsaturated Metal Sites by Direct Implementation of an ab Initio Derived Potential Energy Surface in GCMC Simulation

Chen, L., Grajciar, L., Nachtigall, P., & Düren, T. (2011) · The Journal of Physical Chemistry C · doi:10.1021/jp2090878 · Cited by 98

A Route to Metal–Organic Frameworks through Framework Templating

Wei, Z., Lu, W., Jiang, H., & Zhou, H.-C. “. (2013) · Inorganic Chemistry · doi:10.1021/ic3019937 · Cited by 95

A Facile Post-Synthetic Modification Method To Improve Hydrothermal Stability and CO2 Selectivity of CuBTC Metal–Organic Framework

Al‐Janabi, N., Deng, H., Borges, J., Liu, X., Garforth, A. A., Siperstein, F. R., & Fan, X. (2016) · Industrial & Engineering Chemistry Research · doi:10.1021/acs.iecr.5b04217 · Cited by 93

Influence of the Amide Groups in the CO 2 /N 2 Selectivity of a Series of Isoreticular, Interpenetrated Metal–Organic Frameworks

Safarifard, V., Rodríguez‐Hermida, S., Guillerm, V., Imaz, I., Bigdeli, M., Tehrani, A. A., Juanhuix, J., Morsali, A., Casco, M. E., Silvestre‐Albero, J., et al. (2016) · Crystal Growth & Design · doi:10.1021/acs.cgd.6b01054 · Cited by 93

Doubly Interpenetrated Metal–Organic Framework for Highly Selective C2H2/CH4 and C2H2/CO2 Separation at Room Temperature

Zhang, L., Zou, C., Zhao, M., Jiang, K., Lin, R., He, Y., Wu, C.-D., Cui, Y., Chen, B., & Qian, G. (2016) · Crystal Growth & Design · doi:10.1021/acs.cgd.6b01382 · Cited by 89

CO2 Dynamics in Pure and Mixed-Metal MOFs with Open Metal Sites

Marti, R. M., Howe, J. D., Morelock, C. R., Conradi, M. S., Walton, K. S., Sholl, D. S., & Hayes, S. E. (2017) · The Journal of Physical Chemistry C · doi:10.1021/acs.jpcc.7b07179 · Cited by 87

Multiple Coordination Exchanges for Room-Temperature Activation of Open-Metal Sites in Metal–Organic Frameworks

Bae, J., Choi, J. S., Hwang, S., Yun, W. S., Song, D., Lee, J.-D., & Jeong, N. C. (2017) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.7b07299 · Cited by 86

Comparing van der Waals Density Functionals for CO2 Adsorption in Metal Organic Frameworks

Rana, M. K., Koh, H. S., Hwang, J., & Siegel, D. J. (2012) · The Journal of Physical Chemistry C · doi:10.1021/jp3051164 · Cited by 85

Highly sensitive fluorescent metal-organic framework as a selective sensor of MnVII and CrVI anions (MnO4−/Cr2O72−/CrO42−) in aqueous solutions

Abdollahi, N., & Morsali, A. (2019) · Analytica Chimica Acta · doi:10.1016/j.aca.2019.02.061 · Cited by 84

Synchrotron X-ray studies of metal-organic framework M 2 (2,5-dihydroxyterephthalate), M = (Mn, Co, Ni, Zn) (MOF74)

Wong-Ng, W., Kaduk, J. A., Wu, H., & Suchomel, M. R. (2012) · Powder Diffraction · doi:10.1017/s0885715612000863 · Cited by 82

Fuel purification, Lewis acid and aerobic oxidation catalysis performed by a microporous Co-BTT (BTT3− = 1,3,5-benzenetristetrazolate) framework having coordinatively unsaturated sites

Biswas, S., Maes, M., Dhakshinamoorthy, A., Feyand, M., Vos, D. E. D., García, H., & Stock, N. (2012) · Journal of Materials Chemistry · doi:10.1039/c2jm15592c · Cited by 81

Simulation of the Mechanism of Gas Sorption in a Metal–Organic Framework with Open Metal Sites: Molecular Hydrogen in PCN-61

Forrest, K. A., Pham, T., McLaughlin, K., Belof, J. L., Stern, A. C., Zaworotko, M. J., & Space, B. (2012) · The Journal of Physical Chemistry C · doi:10.1021/jp306084t · Cited by 81

Triple Framework Interpenetration and Immobilization of Open Metal Sites within a Microporous Mixed Metal–Organic Framework for Highly Selective Gas Adsorption

Zhang, Z., Xiang, S., Hong, K., Madhab, C. D., Arman, H. D., García, M. A. L., Mondal, J. U., Thomas, K. M., & Chen, B. (2012) · Inorganic Chemistry · doi:10.1021/ic2021275 · Cited by 81

Drastic Enhancement of Catalytic Activity via Post‐oxidation of a Porous Mn II Triazolate Framework

Liao, P., Li, X., Bai, J., He, C., Zhou, D., Zhang, W., Zhang, J., & Chen, X. (2014) · Chemistry - A European Journal · doi:10.1002/chem.201403123 · Cited by 80

Screening of Copper Open Metal Site MOFs for Olefin/Paraffin Separations Using DFT-Derived Force Fields

Kulkarni, A. R., & Sholl, D. S. (2016) · The Journal of Physical Chemistry C · doi:10.1021/acs.jpcc.6b07493 · Cited by 80

A Robust Metal–Organic Framework Combining Open Metal Sites and Polar Groups for Methane Purification and CO2/Fluorocarbon Capture

Chen, C., Zheng, S., Wei, Z., Cao, C., Wang, H., Wang, D., Jiang, J., Fenske, D., & Su, C. (2017) · Chemistry - A European Journal · doi:10.1002/chem.201606038 · Cited by 80

Critical Factors Driving the High Volumetric Uptake of Methane in Cu3(btc)2

Hulvey, Z., Vlaisavljevich, B., Mason, J. A., Tsivion, E., Dougherty, T. P., Bloch, E. D., Head‐Gordon, M., Smit, B., Long, J. R., & Brown, C. M. (2015) · Journal of the American Chemical Society · doi:10.1021/jacs.5b06657 · Cited by 79

A Soft Copper(II) Porous Coordination Polymer with Unprecedented Aqua Bridge and Selective Adsorption Properties

Procopio, E. Q., Fukushima, T., Barea, E., Navarro, J. A. R., Horike, S., & Kitagawa, S. (2012) · Chemistry - A European Journal · doi:10.1002/chem.201201820 · Cited by 78

A high connectivity metal–organic framework with exceptional hydrogen and methane uptake capacities

Liu, D., Wu, H., Wang, S., Xie, Z., Li, J., & Lin, W. (2012) · Chemical Science · doi:10.1039/c2sc20601c · Cited by 77

Effective CO2 and CO Separation Using [M2(DOBDC)] (M = Mg, Co, Ni) with Unsaturated Metal Sites and Excavation of Their Adsorption Sites

Kim, H., Sohail, M., Yim, K., Park, Y. C., Chun, D. H., Kim, H. J., Han, S. O., & Moon, J.-H. (2019) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.8b20450 · Cited by 76

Investigation of Gas Adsorption Performances and H2Affinities of Porous Metal-Organic Frameworks with Different Entatic Metal Centers

Ma, S., Yuan, D., Chang, J., & Zhou, H.-C. “. (2009) · Inorganic Chemistry · doi:10.1021/ic900475q · Cited by 74

A Versatile Microporous Zinc(II) Metal–Organic Framework for Selective Gas Adsorption, Cooperative Catalysis, and Luminescent Sensing

He, H., Zhang, D., Guo, F., & Sun, F. (2018) · Inorganic Chemistry · doi:10.1021/acs.inorgchem.8b00938 · Cited by 74

Structure–activity relationships of simple molecules adsorbed on CPO-27-Ni metal–organic framework: In situ experiments vs. theory

Valenzano, L., Vitillo, J. G., Chavan, S., Civalleri, B., Bonino, F., Bordiga, S., & Lamberti, C. (2011) · Catalysis Today · doi:10.1016/j.cattod.2011.07.020 · Cited by 73

Predicting Methane Storage in Open-Metal-Site Metal–Organic Frameworks

Koh, H. S., Rana, M. K., Wong‐Foy, A. G., & Siegel, D. J. (2015) · The Journal of Physical Chemistry C · doi:10.1021/acs.jpcc.5b02768 · Cited by 72

Role of Structure and Chemistry in Controlling Separations of CO2/CH4 and CO2/CH4/CO Mixtures over Honeycomb MOFs with Coordinatively Unsaturated Metal Sites

García, E. J., Mowat, J. P. S., Wright, P. A., Pérez‐Pellitero, J., Jallut, C., & Pirngruber, G. D. (2012) · The Journal of Physical Chemistry C · doi:10.1021/jp309526k · Cited by 69

Preferential Adsorption of CO2 in an Ultramicroporous MOF with Cavities Lined by Basic Groups and Open-Metal Sites

Nandi, S., Maity, R., Chakraborty, D., Ballav, H., & Vaidhyanathan, R. (2018) · Inorganic Chemistry · doi:10.1021/acs.inorgchem.8b00304 · Cited by 69

How Well Do Metal–Organic Frameworks Tolerate Flue Gas Impurities?

Ding, L., & Yazaydın, A. Ö. (2012) · The Journal of Physical Chemistry C · doi:10.1021/jp308717y · Cited by 66

On the intrinsic dynamic nature of the rigid UiO-66 metal–organic framework

Hajek, J., Caratelli, C., Demuynck, R., Wispelaere, K. D., Vanduyfhuys, L., Waroquier, M., & Speybroeck, V. V. (2018) · Chemical Science · doi:10.1039/c7sc04947a · Cited by 66

Density Functional Theory-Based Adsorption Isotherms for Pure and Flue Gas Mixtures on Mg-MOF-74. Application in CO2 Capture Swing Adsorption Processes

Alonso, G., Bahamón, D., Keshavarz, F., Giménez, X., Gamallo, P., & Sayós, R. (2018) · The Journal of Physical Chemistry C · doi:10.1021/acs.jpcc.8b00938 · Cited by 66

An experimental and computational study of CO 2 adsorption in the sodalite-type M-BTT (M = Cr, Mn, Fe, Cu) metal–organic frameworks featuring open metal sites

Asgari, M., Jawahery, S., Bloch, E. D., Hudson, M. R., Flacau, R., Vlaisavljevich, B., Long, J. R., Brown, C. M., & Queen, W. L. (2018) · Chemical Science · doi:10.1039/c8sc00971f · Cited by 66

Performance of van der Waals Corrected Functionals for Guest Adsorption in the M2(dobdc) Metal–Organic Frameworks

Vlaisavljevich, B., Huck, J. M., Hulvey, Z., Lee, K., Mason, J. A., Neaton, J. B., Long, J. R., Brown, C. M., Alfè, D., Michaelides, A., et al. (2017) · The Journal of Physical Chemistry A · doi:10.1021/acs.jpca.7b00076 · Cited by 65

Accurate Model for Predicting Adsorption of Olefins and Paraffins on MOFs with Open Metal Sites

Jorge, M., Fischer, M., Gomes, J. R. B., Siquet, C., Santos, J. C., & Rodrigues, A. E. (2014) · Industrial & Engineering Chemistry Research · doi:10.1021/ie500310c · Cited by 61

Neutron Scattering and Spectroscopic Studies of Hydrogen Adsorption in Cr3(BTC)2—A Metal−Organic Framework with Exposed Cr2+ Sites

Sumida, K., Her, J., Dincă, M., Murray, L. J., Schloss, J. M., Pierce, C. J., Thompson, B. A., FitzGerald, S. A., Brown, C. M., & Long, J. R. (2011) · The Journal of Physical Chemistry C · doi:10.1021/jp200638n · Cited by 58

Metal coordination and metal activation abilities of commonly unreactive chloromethanes toward metal–organic frameworks

Bae, J., Lee, E. J., & Jeong, N. C. (2018) · Chemical Communications · doi:10.1039/c8cc02348d · Cited by 58

C 2 H 2 adsorption in three isostructural metal–organic frameworks: boosting C 2 H 2 uptake by rational arrangement of nitrogen sites

Song, C., Jiao, J., Lin, Q., Liu, H., & He, Y. (2016) · Dalton Transactions · doi:10.1039/c5dt04943a · Cited by 57

CO2Adsorption in Fe2(dobdc): A Classical Force Field Parameterized from Quantum Mechanical Calculations

Borycz, J., Lin, L., Bloch, E. D., Kim, J., Dzubak, A. L., Maurice, R., Semrouni, D., Lee, K., Smit, B., & Gagliardi, L. (2014) · The Journal of Physical Chemistry C · doi:10.1021/jp500313j · Cited by 53

Adsorption of Carbon Dioxide on Unsaturated Metal Sites in M2(dobpdc) Frameworks with Exceptional Structural Stability and Relation between Lewis Acidity and Adsorption Enthalpy

Yoo, G. Y., Lee, W. R., Jo, H., Park, J., Song, J. H., Lim, K. S., Moon, D., Jung, H. S., Lim, J., Han, S. S., et al. (2016) · Chemistry - A European Journal · doi:10.1002/chem.201600189 · Cited by 52

Chiral Cadmium(II) Metal–Organic Framework from an Achiral Ligand by Spontaneous Resolution: An Efficient Heterogeneous Catalyst for the Strecker Reaction of Ketones

Verma, A., Tomar, K., & Bharadwaj, P. K. (2017) · Inorganic Chemistry · doi:10.1021/acs.inorgchem.7b01915 · Cited by 49

Carbon dioxide adsorption on MIL-100(M) (M=Cr, V, Sc) metal–organic frameworks: IR spectroscopic and thermodynamic studies

Cabello, C. P., Rumori, P., & Palomino, G. T. (2014) · Microporous and Mesoporous Materials · doi:10.1016/j.micromeso.2014.02.015 · Cited by 48

Adsorption of nitric oxide in metal-organic frameworks: Low temperature IR and EPR spectroscopic evaluation of the role of open metal sites

Barth, B., Mendt, M., Pöppl, A., & Hartmann, M. (2015) · Microporous and Mesoporous Materials · doi:10.1016/j.micromeso.2015.02.020 · Cited by 46

An In‐Depth Structural Study of the Carbon Dioxide Adsorption Process in the Porous Metal–Organic Frameworks CPO‐27‐M

Pato‐Doldán, B., Rosnes, M. H., & Dıetzel, P. D. C. (2017) · ChemSusChem · doi:10.1002/cssc.201601752 · Cited by 46

Enhancing light hydrocarbon storage and separation through introducing Lewis basic nitrogen sites within a carboxylate-decorated copper–organic framework

Liu, X., Fan, W., Zhang, M., Li, G., Liu, H., Sun, D., Zhao, L., Zhu, H., & Guo, W. (2018) · Materials Chemistry Frontiers · doi:10.1039/c8qm00105g · Cited by 46

Ab Initio Adsorption Isotherms for Molecules with Lateral Interactions: CO 2 in Metal–Organic Frameworks

Sillar, K., Kundu, A., & Sauer, J. (2017) · The Journal of Physical Chemistry C · doi:10.1021/acs.jpcc.7b02806 · Cited by 44

Design strategies for metal-organic frameworks selectively capturing harmful gases

Kim, K. C. (2017) · Journal of Organometallic Chemistry · doi:10.1016/j.jorganchem.2017.11.017 · Cited by 44

Metal–Organic Gels Based on a Bisamide Tetracarboxyl Ligand for Carbon Dioxide, Sulfur Dioxide, and Selective Dye Uptake

Dietrich, D., Licht, C. J., Nuhnen, A., Höfert, S., Laporte, L. D., & Janiak, C. (2019) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.9b04659 · Cited by 44

Merging open metal sites and Lewis basic sites in a NbO-type metal–organic framework for improved C 2 H 2 /CH 4 and CO 2 /CH 4 separation

Song, C., Hu, J., Ling, Y., Feng, Y., Chen, D., & He, Y. (2015) · Dalton Transactions · doi:10.1039/c5dt02089a · Cited by 43

MOF-derived, N-doped porous carbon coated graphene sheets as high-performance anodes for lithium-ion batteries

Liu, X., Zhang, S., Xing, Y., Wang, S., Yang, P., & Li, H. (2016) · New Journal of Chemistry · doi:10.1039/c6nj01896c · Cited by 43

Competitive Binding of Ethylene, Water, and Carbon Monoxide in Metal–Organic Framework Materials with Open Cu Sites

You, W., Liu, Y., Howe, J. D., & Sholl, D. S. (2018) · The Journal of Physical Chemistry C · doi:10.1021/acs.jpcc.8b00909 · Cited by 43

Dual activity of durable chiral hydroxyl-rich MOF for asymmetric catalytic reactions

Berijani, K., & Morsali, A. (2019) · Journal of Catalysis · doi:10.1016/j.jcat.2019.08.015 · Cited by 43

Adsorption Characteristics of Metal–Organic Frameworks Containing Coordinatively Unsaturated Metal Sites: Effect of Metal Cations and Adsorbate Properties

Mishra, P. K., Edubilli, S., Mandal, B., & Gumma, S. (2014) · The Journal of Physical Chemistry C · doi:10.1021/jp412622b · Cited by 42

Synthesis and catalytic study of open metal site metal–organic frameworks of Cu3(BTC)2 microbelts in selective organic sulfide oxidation

Rostamnia, S., Alamgholiloo, H., Jafari, M., Rookhosh, R., & Abbasi, A. R. (2016) · Applied Organometallic Chemistry · doi:10.1002/aoc.3528 · Cited by 42

Effects of Open Metal Site Availability on Adsorption Capacity and Olefin/Paraffin Selectivity in the Metal–Organic Framework Cu3(BTC)2

Bentley, J. A., Foo, G. S., Rungta, M., Sangar, N., Sievers, C., Sholl, D. S., & Nair, S. (2016) · Industrial & Engineering Chemistry Research · doi:10.1021/acs.iecr.6b00774 · Cited by 41

Protection of open-metal V(III) sites and their associated CO2/CH4/N2/O2/H2O adsorption properties in mesoporous V-MOFs

Yang, J., Wang, Y., Li, L., Zhang, Z., & Li, J. (2015) · Journal of Colloid and Interface Science · doi:10.1016/j.jcis.2015.06.036 · Cited by 40

Olefin/Paraffin Separation in Open Metal Site Cu-BTC Metal–Organic Framework

Luna‐Triguero, A., Vicent‐Luna, J. M., Gómez‐Álvarez, P., & Calero, S. (2017) · The Journal of Physical Chemistry C · doi:10.1021/acs.jpcc.6b11808 · Cited by 40

Understanding Hydrogen Sorption in In- soc -MOF: A Charged Metal-Organic Framework with Open-Metal Sites, Narrow Channels, and Counterions

Pham, T., Forrest, K. A., Hogan, A., Tudor, B. H., McLaughlin, K., Belof, J. L., Eckert, J., & Space, B. (2015) · Crystal Growth & Design · doi:10.1021/cg5018104 · Cited by 36

Can Metal–Organic Framework Separate 1-Butene from Butene Isomers?

Kim, H., & Jung, Y. (2014) · The Journal of Physical Chemistry Letters · doi:10.1021/jz402734x · Cited by 36

Ligand Torsion Triggered Two Robust Fe‐Tetratopic Carboxylate Frameworks with Enhanced Gas Uptake and Separation Performance

Zhang, J., Hu, M., Li, S., Jiang, Y., & Zhai, Q. (2017) · Chemistry - A European Journal · doi:10.1002/chem.201700867 · Cited by 36

An anionic metal–organic framework constructed from a triazole-functionalized diisophthalate featuring hierarchical cages for selective adsorptive C 2 H 2 /CH 4 and CO 2 /CH 4 separation

Liu, Z., Lv, L., He, Y., & Feng, Y. (2017) · CrystEngComm · doi:10.1039/c7ce00661f · Cited by 36

Improving Olefin Purification Using Metal Organic Frameworks with Open Metal Sites

Luna‐Triguero, A., Vicent‐Luna, J. M., Poursaeidesfahani, A., Vlugt, T. J. H., Sánchez‐de‐Armas, R., Gómez‐Álvarez, P., & Calero, S. (2018) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.8b04106 · Cited by 36

Highly selective separation of small hydrocarbons and carbon dioxide in a metal–organic framework with open copper(ii) coordination sites

Duan, X. L., He, Y., Cui, Y., Yang, Y. L., Krishna, R., Chen, B., & Qian, G. (2014) · RSC Advances · doi:10.1039/c4ra03216k · Cited by 35

Phosphine Gas Adsorption in a Series of Metal–Organic Frameworks

Weston, M. H., Morris, W., Siu, P. W., Hoover, W. J., Cho, D. J., Richardson, R. K., & Farha, O. K. (2015) · Inorganic Chemistry · doi:10.1021/acs.inorgchem.5b01055 · Cited by 35

Effects of Activation Temperature and Densification on Adsorption Performance of MOF MIL-100(Cr)

Yang, J., Bai, H., Zhang, F., Liu, J., Winarta, J., Wang, Y., & Mu, B. (2019) · Journal of Chemical & Engineering Data · doi:10.1021/acs.jced.9b00770 · Cited by 35

Doping of Metal-Organic Frameworks with Functional Guest Molecules and Nanoparticles

Schröder, F., & Fischer, R. A. (2009) · Topics in current chemistry · doi:10.1007/128_2009_4 · Cited by 34

Nitric Oxide Adsorption in Cu3btc2-Type MOFs—Physisorption and Chemisorption as NONOates

Khan, A. H., Peikert, K., Hoffmann, F., Fröba, M., & Bertmer, M. (2019) · The Journal of Physical Chemistry C · doi:10.1021/acs.jpcc.8b11919 · Cited by 33

Predictive models of gas sorption in a metal–organic framework with open-metal sites and small pore sizes

Pham, T., Forrest, K. A., Franz, D., Guo, Z., Chen, B., & Space, B. (2017) · Physical Chemistry Chemical Physics · doi:10.1039/c7cp02767b · Cited by 29

Microporous metal-organic frameworks with suitable pore spaces for acetylene storage and purification

Xia, T., Cai, J., Wang, H., Duan, X. L., Cui, Y., Yang, Y. L., & Qian, G. (2015) · Microporous and Mesoporous Materials · doi:10.1016/j.micromeso.2015.05.036 · Cited by 26

Elucidating the Interaction of CO2 in the Giant Metal–Organic Framework MIL-100 through Large-Scale Periodic Ab Initio Modeling

D’Amore, M., Civalleri, B., Bush, I. J., Albanese, E., & Ferrabone, M. (2019) · The Journal of Physical Chemistry C · doi:10.1021/acs.jpcc.9b06533 · Cited by 24

An In‐Situ Neutron Diffraction and DFT Study of Hydrogen Adsorption in a Sodalite‐Type Metal–Organic Framework, Cu‐BTTri

Asgari, M., Semino, R., Schouwink, P., Kochetygov, I., Trukhina, O. N., Tarver, J., Bulut, S., Yang, S., Brown, C. M., Ceriotti, M., et al. (2018) · European Journal of Inorganic Chemistry · doi:10.1002/ejic.201801253 · Cited by 21

A Distorted [Mn2(COO)4N2] Cluster Based Metal–Organic Framework with (3,3,6) Topology and Selective Adsorption of CO2

Jiang, J., Wang, Q., Zhang, M., & Bai, J. (2017) · Crystal Growth & Design · doi:10.1021/acs.cgd.7b00206 · Cited by 20

Identifying the Interactions That Allow Separation of O2 from N2 on the Open Iron Sites of Fe2(dobdc)

Verma, P., Maurice, R., & Truhlar, D. G. (2015) · The Journal of Physical Chemistry C · doi:10.1021/acs.jpcc.5b10382 · Cited by 18

Sorption of H2 to Open Metal Sites in a Metal–Organic Framework: A Symmetry-Adapted Perturbation Theory Analysis

Goings, J. J., Ohlsen, S. M., Blaisdell, K. M., & Schofield, D. P. (2014) · The Journal of Physical Chemistry A · doi:10.1021/jp412779q · Cited by 14

Effect of Pore Size, Solvation, and Defectivity on the Perturbation of Adsorbates in MOFs: The Paradigmatic Mg2(dobpdc) Case Study

Vitillo, J. G., & Ricchiardi, G. (2017) · The Journal of Physical Chemistry C · doi:10.1021/acs.jpcc.7b06252 · Cited by 13

Adsorption of Natural Gas Methane on Metal-Organic Framework Structures in the Range of Supercritical Temperatures

Фомкин, А. А., Tsivadze, A. Y., Aksyutin, O. E., Ишков, А. Г., Прибылов, А. А., Shkolin, A. V., Men’shchikov, I. E., Romanov, K. V., Викторович, Т. Р., Müller, U., et al. (2018) · Protection of Metals and Physical Chemistry of Surfaces · doi:10.1134/s2070205118010069 · Cited by 12

Reversible structural transformations in a Co(II)-based 2D dynamic metal-organic framework showing selective solvent uptake

Nagarkar, S. S., & Ghosh, S. K. (2015) · Journal of Chemical Sciences · doi:10.1007/s12039-015-0820-3 · Cited by 8

A foundation model for atomistic materials chemistry

Batatia, I., Benner, P., Chiang, Y., Elena, A. M., Kovács, D. P., Riebesell, J., Advincula, X. R., Asta, M., Avaylon, M., Baldwin, W. J., et al. (2024) · arXiv · doi:10.48550/arxiv.2401.00096 · Cited by 604

Understanding the Effect of Water on CO2 Adsorption

Kolle, J. M., Fayaz, M., & Sayari, A. (2021) · Chemical Reviews · doi:10.1021/acs.chemrev.0c00762 · Cited by 523