Clean rhodium nanoparticles prepared by laser ablation in liquid for high performance electrocatalysis of the hydrogen evolution reaction
Open accessAbstract
Rhodium nanoparticles prepared by a facile laser ablation procedure show excellent activity towards the hydrogen evolution reaction.
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HER reaction kinetics in alkaline or neutral media is much lower than in acidic media.
“Generally, HER reaction kinetics in alkaline or neutral media is much lower than that in acidic media.[18,19]”
From Functionalized Ultrafine Rhodium Nanoparticles on Graphene Aerogels for the Hydrogen Evolution Reaction (2021) · cites this paper as [18]
The passages labeled Abstract (page unavailable) report that both Rh catalysts required greater overpotential to reach −10 mA cm−2 in alkaline KOH than in acidic H2SO4, supporting slower HER performance for those catalysts under alkaline conditions. The paper does not address neutral media, and its catalyst-specific comparison does not establish the claim as a general rule. (LLM, conf=0.85)
Experimental — accuracy not yet measuredThe poor durability of the commercial 20% Pt/C electrocatalyst may originate from weak cohesion between the carbon substrate and Pt nanoparticles, which results in aggregation and/or exfoliation of nanoparticles.
“The poor durability of commercial 20% Pt/C electrocatalyst may originate from the weak cohesion between carbon substrate and Pt nanoparticles, which easily results in the aggregation and/or exfoliation of nanoparticles.[18]”
From Functionalized Ultrafine Rhodium Nanoparticles on Graphene Aerogels for the Hydrogen Evolution Reaction (2021) · cites this paper as [18]
The stability passage (page not specified) attributes poor stability of Rh/C inks during cycling to adhesion of the ink coating to a glassy-carbon electrode. The passages comparing commercial Pt/C report electrocatalytic performance, not its durability. A search for Pt/C durability and nanoparticle cohesion found no passage linking weak Pt–carbon cohesion to aggregation or exfoliation. (LLM, conf=0.74)
Experimental — accuracy not yet measured
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“However, the electrocatalysts with the aforementioned characteristics, such as Pt [18], Re [19], Pd [20], Ir [21], Rh [22] and Au [12], are noble metals that are both scarce and expensive, hindering their industrialization [23–25].”
BackgroundZhao, X., He, X., Yin, F., Chen, B., Li, G., & Yin, H. (2020) · International Journal of Hydrogen Energy · doi:10.1016/j.ijhydene.2020.04.046 · Cited by 9 · see citing works
- Authors
- Volpato, G. A., Muneton Arboleda, D., Brandiele, R., Carraro, F., Sartori, G. B., Cardelli, A., Badocco, D., Pastore, P., Agnoli, S., Durante, C., Amendola, V., & Sartorel, A.
- Affiliations
- University of Padua (IT)
- Centro de Investigaciones Ópticas CIOp (CONICET-CIC-UNLP)
- Corresponding author
- Durante, Christian
- Amendola, Vincenzo
- Sartorel, Andrea
- ORCID
- Venue
- Nanoscale Advances
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2019
- Volume
- 1
- Issue
- 11
- Pages
- 4296-4300
- ISSN
- 2516-0230 (ISSN-L)
- PMC
- PMC9417491
- OpenAlex
- W2981080718
- Cited by
- 22
- References
- 32
- Citations by year
- 2026: 1 · 2025: 1 · 2024: 4 · 2023: 4 · 2022: 3 · 2021: 6 · 2020: 3
- FWCI
- 1.06
- Type
- journal article
- Language
- en
- Open access
- gold
- doi.org
- Licence
- Locations
- Nanoscale Advances (publishedVersion, cc-by-nc)
- PubMed Central (publishedVersion, cc-by-nc)
- PubMed (publishedVersion)
- Conicet (submittedVersion, cc-by-nc)
- Padua Research Archive (University of Padova) (submittedVersion, cc-by-nc)
- INFM-OAR (INFN Catania) (submittedVersion, cc-by-nc)
- Zenodo (CERN European Organization for Nuclear Research) (cc-by)
- Funders
- Università degli Studi di Padova (Iniziative di Cooperazione Universitaria 2017, PHOETRY, P-DiSC #10BIRD2018-UNIPD, STARS grant “4NANOMED”)
- Ministero degli Affari Esteri e della Cooperazione Internazionale (Italy-Argentine Great relevance project)
- Fondazione Cassa di Risparmio di Padova e Rovigo
- Topics
- Physical Sciences › Engineering › Biomedical Engineering › Laser-Ablation Synthesis of Nanoparticles
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › Electrocatalysts for Energy Conversion
- Physical Sciences › Materials Science › Materials Chemistry › Advanced Nanomaterials in Catalysis
- Keywords
- rhodium nanoparticles, laser ablation in liquid, hydrogen evolution reaction, electrocatalysis, water-based synthesis
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