MOF-derived cobalt–nickel phosphide nanoboxes as electrocatalysts for the hydrogen evolution reaction
Abstract
The CoNi-MOF which was synthesised using a Co-MOF was converted into a CoNiP nanobox by low temperature phosphating. The CoNiP nanobox exhibits outstanding catalytic activity and long durability for the HER in alkaline electrolytes.
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The positive shift in Co 2p XPS signals after phosphorization is attributed to partial electron transfer from Co to P.
“the obviously positive shift could be observed in the spectrum of both Co signals after phosphorylating treatment, which may be attributed to the partial electron transfer from Co to P.53”
From Bimetallic (Co/Ni) MOF-Derived CoNiP Hierarchically Porous Carbon Monolithic Aerogel for the Hydrolysis of Ammonia Borane (2024) · cites this paper as [53]
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References 75 · Cited by 111
- Authors
- Lu, Y., Deng, Y., Lu, S., Liu, Y., Lang, J., Cao, X., & Gu, H.
- Affiliations
- Soochow University (CN)
- Changzhou Institute of Technology (CN)
- Jiangnan University (CN)
- College of Chemistry
- Corresponding author
- Cao, Xueqin
- Gu, Hongwei
- Venue
- Nanoscale
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2019
- Volume
- 11
- Issue
- 44
- Pages
- 21259-21265
- ISSN
- 2040-3364 (ISSN-L)
- 2040-3372
- OpenAlex
- W2977431601
- Cited by
- 111
- References
- 75
- Citations by year
- 2026: 5 · 2025: 8 · 2024: 21 · 2023: 12 · 2022: 27 · 2021: 20 · 2020: 16 · 2019: 1 · 2018: 1
- FWCI
- 3.41
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Nanoscale (publishedVersion)
- PubMed (publishedVersion)
- Funders
- Suzhou Municipal Science and Technology Bureau (SYG201732)
- Priority Academic Program Development of Jiangsu Higher Education Institutions
- Natural Science Research of Jiangsu Higher Education Institutions of China (17KJB430029)
- Topics
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › Electrocatalysts for Energy Conversion
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › CO2 Reduction Techniques and Catalysts
- Physical Sciences › Materials Science › Materials Chemistry › Hydrogen Storage and Materials
- Keywords
- metal-organic framework derived materials, hydrogen evolution reaction, electrocatalysts, phosphating, alkaline electrolyte, catalyst stability
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