LXXIII.—Oxidation of tartaric acid in presence of iron
Abstract
H. J. H. Fenton, J. Chem. Soc., Trans., 1894, 65, 899 DOI: 10.1039/CT8946500899
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OH· is generally formed as a product of Fenton reactions involving free iron or copper ions and hydrogen peroxide or from the reaction of hydrogen peroxide with superoxide (Haber-Weiss reaction).
“In this context, OH· is generally formed as a product of Fenton reactions involving free iron or copper ions (Fe2+; Cu+) and hydrogen peroxide (Eq. 26) (281, 986) or from the reaction of hydrogen peroxide with superoxide (Haber–Weiss reaction) (Eq. 27) (394).”
From Sources of Vascular Nitric Oxide and Reactive Oxygen Species and Their Regulation (2019) · cites this paper as [281]
Heme-mediated cytotoxicity occurs via a Fenton reaction producing hydroxyl radicals.
“Presumably, this occurs via a mechanism driven via the Fenton reaction in which hydrogen peroxide (H 2 O 2 ) oxidizes Fe 2+ , either within the context of the tetrapyrrole ring or when Fe is released from heme, to produce highly reactive hydroxyl radicals (OH .) [38,212].”
From The Iron age of host–microbe interactions (2015) · cites this paper as [212]
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Cited by 3,179
- Authors
- Fenton, H. J. H.
- Corresponding author
- Fenton, H. J. H.
- Venue
- J. Chem. Soc., Trans.
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 1894
- Volume
- 65
- Issue
- 0
- Pages
- 899-910
- ISSN
- 0368-1645 (ISSN-L)
- OpenAlex
- W2004283265
- Cited by
- 3,179
- References
- 0
- Citations by year
- 2026: 111 · 2025: 144 · 2024: 167 · 2023: 177 · 2022: 184 · 2021: 195 · 2020: 194 · 2019: 148 · 2018: 163 · 2017: 134 · 2016: 126 · 2015: 116 · 2014: 137 · 2013: 111 · 2012: 108
- FWCI
- 0.00
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Journal of the Chemical Society Transactions (publishedVersion)
- Topics
- Physical Sciences › Chemistry › Organic Chemistry › Oxidative Organic Chemistry Reactions
- Physical Sciences › Chemistry › Organic Chemistry › Inorganic and Organometallic Chemistry
- Physical Sciences › Chemistry › Organic Chemistry › Chemical Reaction Mechanisms
- Keywords
- tartaric acid, oxidation, iron, iron catalysis, redox reactions
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