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Cited by 146Advanced Photocatalysis TechniquesOrganic Electronics and PhotovoltaicsElectrocatalysts for Energy Conversion

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Side-chain tuning in conjugated polymer photocatalysts for improved hydrogen production from water

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Woods, Duncan J., Hillman, Sam A. J., Pearce, Drew, Wilbraham, Liam, Flagg, Lucas Q., Duffy, Warren, McCulloch, Iain, Durrant, James R., Guilbert, Anne A. Y., Zwijnenburg, Martijn A., Sprick, Reiner Sebastian, Nelson, Jenny, Cooper, Andrew I.·2020·Energy & Environmental Science
DOI 10.1039/d0ee01213k
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Abstract

Structure–property–activity relationships in solution processable polymer photocatalysts for hydrogen production from water were probed by varying the chemical structure of both the polymer side-chains and the polymer backbone.

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  • The photocatalytic aerogel achieved a hydrogen generation rate of 60.7 mmol m−2 h−1, significantly outperforming conventional thin-film photocatalytic platforms.

    “As a result, the photocatalytic aerogels achieved a high hydrogen generation rate of 60.7 mmol m 2 h 1 , significantly outperforming the conventional thin-film photocatalytic platforms.”

    From Gradient-structured directional porous floatable aerogels for effective solar-driven hydrogen production and steam generation (2025) · cites this paper as [59]

    The ‘Polymer photocatalysts on supports’ section reports hydrogen evolution rates for thin FS-TEG films, including 9.6 ± 0.2 mmol m−2 h−1 for three stacked slides. This provides a thin-film benchmark, but the paper does not report a photocatalytic aerogel, a rate of 60.7 mmol m−2 h−1, or a direct aerogel–film comparison. (LLM, conf=0.87)

    Experimental — accuracy not yet measured

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References 56 · Cited by 146

Research works printed but not linked: 55

  1. Chen, 2010, Chem. Rev., 110, 6503, 10.1021/cr1001645 · DOI · Paper page
  2. Li, 2010, Adv. Funct. Mater., 20, 3390, 10.1002/adfm.201000604 · DOI
  3. Praveen Kumar, 2013, Chem. Commun., 49, 9443, 10.1039/c3cc44742a · DOI
  4. Rosseler, 2010, J. Catal., 269, 179, 10.1016/j.jcat.2009.11.006 · DOI
  5. Brabec, 2004, Sol. Energy Mater. Sol. Cells, 83, 273, 10.1016/j.solmat.2004.02.030 · DOI
  6. Zhang, 2016, Angew. Chem., Int. Ed., 55, 15712, 10.1002/anie.201607375 · DOI
  7. Jayakumar, 2020, ChemCatChem, 12, 689, 10.1002/cctc.201901725 · DOI
  8. Sprick, 2016, Angew. Chem., Int. Ed., 55, 1792, 10.1002/anie.201510542 · DOI
  9. Yang, 2016, Angew. Chem., Int. Ed., 55, 9202, 10.1002/anie.201603532 · DOI
  10. Sprick, 2018, J. Mater. Chem. A, 6, 11994, 10.1039/C8TA04186E · DOI
  11. Tseng, 2018, ACS Catal., 8, 7766, 10.1021/acscatal.8b01678 · DOI
  12. Martin, 2014, J. Am. Chem. Soc., 136, 12568, 10.1021/ja506386e · DOI
  13. Liu, 2015, Science, 347, 970, 10.1126/science.aaa3145 · DOI · Paper page
  14. Stegbauer, 2014, Chem. Sci., 5, 2789, 10.1039/C4SC00016A · DOI
  15. Vyas, 2015, Nat. Commun., 6, 8508, 10.1038/ncomms9508 · DOI
  16. Wang, 2018, Nat. Chem., 10, 1180, 10.1038/s41557-018-0141-5 · DOI · Paper page
  17. Schwinghammer, 2015, Energy Environ. Sci., 8, 3345, 10.1039/C5EE02574E · DOI
  18. Bi, 2015, Macromol. Rapid Commun., 36, 1799, 10.1002/marc.201500270 · DOI
  19. Meier, 2019, Chem. Mater., 31, 8830, 10.1021/acs.chemmater.9b02825 · DOI
  20. Sprick, 2015, J. Am. Chem. Soc., 137, 3265, 10.1021/ja511552k · DOI
  21. Li, 2016, J. Am. Chem. Soc., 138, 7681, 10.1021/jacs.6b03472 · DOI
  22. Sprick, 2016, Chem. Commun., 52, 10008, 10.1039/C6CC03536A · DOI
  23. Zhang, 2016, Chem. Sci., 7, 3062, 10.1039/C5SC04572J · DOI
  24. Pan, 2017, ChemSusChem, 10, 87, 10.1002/cssc.201600850 · DOI
  25. Wu, 2017, ACS Catal., 7, 1637, 10.1021/acscatal.6b03244 · DOI
  26. Wang, 2017, Adv. Mater., 29, 1702428, 10.1002/adma.201702428 · DOI
  27. Wang, 2018, Angew. Chem., Int. Ed., 57, 3454, 10.1002/anie.201710557 · DOI
  28. Woods, 2017, Adv. Energy Mater., 7, 1700479, 10.1002/aenm.201700479 · DOI
  29. Sachs, 2018, Nat. Commun., 9, 4968, 10.1038/s41467-018-07420-6 · DOI
  30. Sprick, 2019, Chem. Mater., 31, 305, 10.1021/acs.chemmater.8b02833 · DOI
  31. Hu, 2019, iScience, 13, 33, 10.1016/j.isci.2019.02.007 · DOI
  32. Sprick, 2020, J. Mater. Chem. A, 8, 7125, 10.1039/D0TA01200A · DOI
  33. Bai, 2019, J. Am. Chem. Soc., 141, 9063, 10.1021/jacs.9b03591 · DOI
  34. Sprick, 2018, Chem. Mater., 30, 5733, 10.1021/acs.chemmater.8b02501 · DOI
  35. Meng, 2015, Macromolecules, 48, 4357, 10.1021/acs.macromol.5b00702 · DOI
  36. Kang, 2008, Polymer, 49, 5700, 10.1016/j.polymer.2008.10.006 · DOI
  37. Blondin, 2000, Macromolecules, 33, 5874, 10.1021/ma000020l · DOI
  38. W. Brütting , Physics of Organic Semiconductors , 2006
  39. Aitchison, 2019, J. Mater. Chem. A, 7, 2490, 10.1039/C8TA11383A · DOI
  40. Nistor, 2011, Rev. Mater. Plast., 48, 33
  41. Guiglion, 2014, J. Mater. Chem. A, 2, 11996, 10.1039/C4TA02044H · DOI
  42. Guiglion, 2017, J. Phys. Chem. C, 121, 1498, 10.1021/acs.jpcc.6b11133 · DOI
  43. Schäfer, 1992, J. Chem. Phys., 97, 2571, 10.1063/1.463096 · DOI
  44. Becke, 1993, J. Chem. Phys., 98, 5648, 10.1063/1.464913 · DOI · Paper page
  45. Lee, 1988, Phys. Rev. B: Condens. Matter Mater. Phys., 37, 785, 10.1103/PhysRevB.37.785 · DOI · Paper page
  46. Stephens, 1994, J. Phys. Chem., 98, 11623, 10.1021/j100096a001 · DOI
  47. Klamt, 1993, J. Chem. Soc., Perkin Trans. 2, 799, 10.1039/P29930000799 · DOI
  48. Guo, 2019, ACS Catal., 9, 9438, 10.1021/acscatal.9b01951 · DOI
  49. Sprick, 2013, J. Mater. Chem. C, 1, 3327, 10.1039/c3tc30368c · DOI
  50. Li, 2013, J. Colloid Interface Sci., 392, 369, 10.1016/j.jcis.2012.08.078 · DOI
  51. Xu, 2001, Phys. Rev. B: Condens. Matter Mater. Phys., 64, 193201, 10.1103/PhysRevB.64.193201 · DOI
  52. Pastor, 2017, Nat. Commun., 8, 14280, 10.1038/ncomms14280 · DOI
  53. Reynal, 2013, Energy Environ. Sci., 6, 3291, 10.1039/c3ee40961a · DOI
  54. Rodenberg, 2015, Inorg. Chem., 54, 646, 10.1021/ic502591a · DOI
  55. Dimitrov, 2016, Polymers, 8, 14, 10.3390/polym8010014 · DOI

Metadata

Authors
Woods, D. J., Hillman, S. A. J., Pearce, D., Wilbraham, L., Flagg, L. Q., Duffy, W., McCulloch, I., Durrant, J. R., Guilbert, A. A. Y., Zwijnenburg, M. A., Sprick, R. S., Nelson, J., & Cooper, A. I.
Affiliations
  • University of Liverpool (GB)
  • Imperial College London (GB)
  • University College London (GB)
  • University of Washington (US)
  • King Abdullah University of Science and Technology (SA)
Corresponding author
  • Zwijnenburg, Martijn A.
  • Sprick, Reiner Sebastian
  • Nelson, Jenny
  • Cooper, Andrew I.
ORCID
Venue
Energy & Environmental Science
Publisher
Royal Society of Chemistry (RSC)
Published
2020
Volume
13
Issue
6
Pages
1843-1855
ISSN
  • 1754-5692 (ISSN-L)
  • 1754-5706
DOI
10.1039/d0ee01213k
OpenAlex
W3023581104
Cited by
146
References
56
Citations by year
2026: 12 · 2025: 21 · 2024: 27 · 2023: 19 · 2022: 28 · 2021: 31 · 2020: 8
FWCI
4.24
Type
journal article
Language
en
Open access
Licence
Locations
  • Energy & Environmental Science (publishedVersion, cc-by)
  • Strathprints: The University of Strathclyde institutional repository (University of Strathclyde) (acceptedVersion)
  • UCL Discovery (University College London) (submittedVersion)
  • King Abdullah University of Science and Technology Repository (King Abdullah University of Science and Technology) (submittedVersion, cc-by)
  • Spiral (Imperial College London) (submittedVersion, cc-by)
Funders
  • European Commission (Grant Agreement No 742708)
  • Engineering and Physical Sciences Research Council (EP/L016702/1, EP/N004884/1, EP/P005543/1, EP/P00928X/1, EP/R023581/1)
  • National Science Foundation (NSF DMR-1607242, award number 1629369)
  • King Abdullah University of Science and Technology (OSR-2015-CRG4-2572)
Topics
  • Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › Advanced Photocatalysis Techniques
  • Physical Sciences › Engineering › Electrical and Electronic Engineering › Organic Electronics and Photovoltaics
  • Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › Electrocatalysts for Energy Conversion
Keywords
conjugated polymers, polymer photocatalysts, hydrogen production, water splitting, structure-property-activity relationship, solution-processable polymers, polymer backbone, photocatalytic hydrogen evolution

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