Asymmetric autocatalysis triggered by triglycine sulfate with switchable chirality by altering the direction of the applied electric field
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In asymmetric autocatalysis with amplification of ee, molecular chirality of highly enantioenriched organic compounds is controlled by a crystal TGS, whose chirality is switchable by changing the direction of the applied static electric field.
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Enantio-enriched or enantiopure pyrimidine alcohol was generated with determined configuration when the autocatalytic Soai reaction was initiated with chiral crystals such as quartz, gamma-glycine, cinnabar, anhydrous cytosine, triglycine sulfate, or with enantiotopic faces of achiral crystals such as gypsum.
“Enantio-enriched or enantiopure pyrimidine alcohol was generated with determined configuration when the auto-catalytic reaction was initiated with chiral crystals, such as (a)-quartz, 406 g-glycine, 407 N-(2-thienylcarbonyl)glycine, 408 cinnabar, 409 anhydrous cytosine, 292 or triglycine sulfate, 410 or with enantiotopic faces of achiral crystals such as CaSO 4 Á2H 2 O (gypsum).411”
From Possible chemical and physical scenarios towards biological homochirality (2022) · cites this paper as [410]
Cites
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Self-citationAsymmetric Autocatalysis Triggered by Carbon Isotope ( <sup>13</sup> C/ <sup>12</sup> C) Chirality
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Self-citationOscillatory Symmetry Breaking in the Soai Reaction
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Self-citationRole of Asymmetric Autocatalysis in the Elucidation of Origins of Homochirality of Organic Compounds
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Possible chemical and physical scenarios towards biological homochirality
Sallembien, Q., Bouteiller, L., Crassous, J., & Raynal, M. (2022) · Chemical Society Reviews · doi:10.1039/d1cs01179k · Cited by 186 · see citing works
- Authors
- Kawasaki, T., Kaimori, Y., Shimada, S., Hara, N., Sato, S., Suzuki, K., Asahi, T., Matsumoto, A., & Soai, K.
- Affiliations
- Tokyo University of Science (JP)
- Waseda University (JP)
- Corresponding author
- Soai, Kenso
- Venue
- Chemical Communications
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2021
- Volume
- 57
- Issue
- 49
- Pages
- 5999-6002
- ISSN
- 1359-7345 (ISSN-L)
- 1364-548X
- OpenAlex
- W3161159845
- Cited by
- 14
- References
- 17
- Citations by year
- 2026: 1 · 2025: 2 · 2024: 1 · 2022: 8 · 2021: 2
- FWCI
- 1.09
- Type
- journal article
- Language
- en
- Open access
- hybrid
- doi.org
- Licence
- Locations
- Chemical Communications (publishedVersion, cc-by-nc)
- PubMed (publishedVersion)
- Funders
- Japan Society for the Promotion of Science (15H03781, 18H04518, 19K05482, 19K22190, 23685012, 26810026, 15J03968)
- Topics
- Physical Sciences › Chemistry › Organic Chemistry › Asymmetric Synthesis and Catalysis
- Physical Sciences › Physics and Astronomy › Astronomy and Astrophysics › Origins and Evolution of Life
- Physical Sciences › Engineering › Biomedical Engineering › Surface Chemistry and Catalysis
- Keywords
- triglycine sulfate, asymmetric autocatalysis, Soai reaction, ferroelectric crystals, electric field control, polarization, enantiomeric excess, chirality control
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