Electrochemical reduction of carbon dioxide with nearly 100% carbon monoxide faradaic efficiency from vacancy-stabilized single-atom active sites
Abstract
Unsaturated Ni centers are prepared through a CO 2 -to-carbon process and exhibit promising performance for electrochemical CO 2 reduction. As cathodes in flow cells, the catalysts exhibit nearly 100% selectivity for CO formation under a high current density of 51 mA cm −2 .
Integrity signals
Registry
Cites
Statistics
Claims the paper makes
Claims other papers make about this one
Each is checked against this paper’s own text: does it say what the citing paper says it does?
DFT calculation is a major means to investigate the mechanism of the electrocatalytic reaction.
“DFT calculation is a major means to investigate the mechanism of the electrocatalytic reaction [49,50].”
From Partially oxidized ruthenium aerogel as highly active bifunctional electrocatalyst for overall water splitting in both alkaline and acidic media (2022) · cites this paper as [50]
Cites
Enhanced electrocatalytic CO2 reduction via field-induced reagent concentration
Liu, M., Pang, Y., Zhang, B., De Luna, P., Voznyy, O., Xu, J., Zheng, X., Dinh, C. T., Fan, F., Cao, C., et al. (2016) · Nature · doi:10.1038/nature19060 · Cited by 2,000 · see citing works
Ionic Liquid–Mediated Selective Conversion of CO <sub>2</sub> to CO at Low Overpotentials
Rosen, B. A., Salehi-Khojin, A., Thorson, M. R., Zhu, W., Whipple, D. T., Kenis, P. J. A., & Masel, R. I. (2011) · Science · doi:10.1126/science.1209786 · Cited by 1,558 · see citing works
Domino electroreduction of CO2 to methanol on a molecular catalyst
Wu, Y., Jiang, Z., Lu, X., Liang, Y., & Wang, H. (2019) · Nature · doi:10.1038/s41586-019-1760-8 · Cited by 1,194 · see citing works
Large-Scale and Highly Selective CO2 Electrocatalytic Reduction on Nickel Single-Atom Catalyst
Zheng, T., Jiang, K., Ta, N., Hu, Y., Zeng, J., Liu, J., & Wang, H. (2019) · Joule · doi:10.1016/j.joule.2018.10.015 · Cited by 887 · see citing works
Self-citation
Flagged first, then by citations
Cited by
Sorted by citations
Yan, S., Liao, W., Zhong, M., Li, W., Wang, C., Pinna, N., Chen, W., & Lu, X. (2022) · Applied Catalysis B: Environment and Energy · doi:10.1016/j.apcatb.2022.121199 · Cited by 106 · see citing works
Self-citation
- Authors
- Lu, C., Jiang, K., Tranca, D., Wang, N., Zhu, H., Rodríguez-Hernández, F., Chen, Z., Yang, C., Zhang, F., Su, Y., Ke, C., Zhang, J., Han, Y., & Zhuang, X.
- Affiliations
- Shanghai Jiao Tong University (CN)
- Beijing University of Technology (CN)
- King Abdullah University of Science and Technology (SA)
- Departamento de Química, Universidad Autónoma de Madrid, Módulo 13, 28049 Madrid, Spain
- Chinese Academy of Sciences (CN)
- Corresponding author
- Zhang, Fan
- Ke, Changchun
- Zhang, Jichao
- Zhuang, Xiaodong
- ORCID
- Venue
- Journal of Materials Chemistry A
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2021
- Volume
- 9
- Issue
- 44
- Pages
- 24955-24962
- ISSN
- 2050-7488 (ISSN-L)
- 2050-7496
- OpenAlex
- W3205795914
- Cited by
- 46
- References
- 4
- Citations by year
- 2026: 3 · 2025: 8 · 2024: 7 · 2023: 16 · 2022: 12
- FWCI
- 1.64
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Journal of Materials Chemistry A (publishedVersion)
- King Abdullah University of Science and Technology Repository (King Abdullah University of Science and Technology) (submittedVersion)
- Funders
- National Natural Science Foundation of China (51973114, 21720102002, 51811530013, 11705270, 11975100, 21406220)
- National Key Research and Development Program of China (2017YFE9134000)
- Science and Technology Commission of Shanghai Municipality (19JC412600)
- Topics
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › CO2 Reduction Techniques and Catalysts
- Physical Sciences › Chemical Engineering › Catalysis › Catalysts for Methane Reforming
- Physical Sciences › Chemical Engineering › Process Chemistry and Technology › Carbon dioxide utilization in catalysis
- Keywords
- electrochemical CO2 reduction, CO selectivity, single-atom catalysts, nickel catalysts, flow cell, high current density
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
