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Theory of the differential capacity of the oxide/aqueous electrolyte interface
Abstract
The conditions under which an oxide surface in aqueous solution will obey the Nernst equation with respect to H+/OH– as potential-determining ions are investigated and a modified form of the Nernst equation is derived. This is combined with a model of the inner part of the double layer involving adsorption of both anions and cations of a supporting uni-univalent electrolyte and a discreteness-of-charge correction in their adsorption isotherms. Theoretical total differential capacities at the interface are compared with experimental data for TiO2 and SiO2.
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Cited by
Toward the rational design of non-precious transition metal oxides for oxygen electrocatalysis
Hong, W. T., Risch, M., Stoerzinger, K. A., Grimaud, A., Suntivich, J., & Shao-Horn, Y. (2015) · Energy & Environmental Science · doi:10.1039/c4ee03869j · Cited by 2,089
NixCo3−xO4 Nanowire Arrays for Electrocatalytic Oxygen Evolution
Li, Y., Hasin, P., & Wu, Y. (2010) · Advanced Materials · doi:10.1002/adma.200903896 · Cited by 894
Metadata
- Authors
- Levine, S., & Smith, A. L.
- Venue
- Discussions of the Faraday Society
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 1971
- Volume
- 52
- Pages
- 290
- ISSN
- 0366-9033 (ISSN-L)
- OpenAlex
- W2009393911
- Cited by
- 325
- References
- 0
- FWCI
- 2.16
- Type
- journal article
- Language
- en
- Open access
- closed
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- CoChat. (2026). Citation check: Theory of the differential capacity of the oxide/aqueous electrolyte interface. https://app.cochat.ai/papers/10.1039/df9715200290
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- Levine, S., & Smith, A. L. (1971). Theory of the differential capacity of the oxide/aqueous electrolyte interface. Discussions of the Faraday Society. https://doi.org/10.1039/df9715200290
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Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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