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Hydrogen generation by hydrolysis of sodium tetrahydroborate: effects of acids and transition metals and their salts
Abstract
A study was undertaken in order to investigate the potential of NaBH4 as a precursor fuel source for a hydrogen–oxygen (air) fuel cell. At appropriate initial acid concentration, hydrolysis of NaBH4 is nearly 80% complete in 2.5 min, and nearly 90% complete in 10 min at 21.7 °C. Transition metals and their salts also accelerate hydrolysis of NaBH4. The effect of transition metals is characterized by zero-order kinetics.
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Citations
Cited by
Xu, Q., & Chandra, M. (2006) · Journal of Power Sources · doi:10.1016/j.jpowsour.2006.09.043 · Cited by 601
An ultrasafe hydrogen generator: aqueous, alkaline borohydride solutions and Ru catalyst
Amendola, S. C., Sharp-Goldman, S. L., Janjua, M. S., Kelly, M. T., Petillo, P. J., & Binder, M. (2000) · Journal of Power Sources · doi:10.1016/s0378-7753(99)00301-8 · Cited by 549
Hua, D. (2003) · International Journal of Hydrogen Energy · doi:10.1016/s0360-3199(02)00235-5 · Cited by 355
Demirci, U. B., Akdim, O., Andrieux, J., Hannauer, J., Chamoun, R., & Miele, P. (2010) · Fuel Cells · doi:10.1002/fuce.200800171 · Cited by 315
Zhao (2007) · doi:10.1016/j.ijhydene.2007.07.004 · Cited by 261
Metadata
- Authors
- Kaufman, C. M., & Sen, B.
- Venue
- Journal of the Chemical Society, Dalton Transactions
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 1985
- Issue
- 2
- Pages
- 307
- ISSN
- 1364-5447 (ISSN-L)
- 0300-9246
- OpenAlex
- W1988104565
- Cited by
- 270
- References
- 0
- FWCI
- 0.95
- Type
- journal article
- Language
- en
- Open access
- closed
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- CoChat. (2026). Citation check: Hydrogen generation by hydrolysis of sodium tetrahydroborate: effects of acids and transition metals and their salts. https://app.cochat.ai/papers/10.1039/dt9850000307
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- Kaufman, C. M., & Sen, B. (1985). Hydrogen generation by hydrolysis of sodium tetrahydroborate: effects of acids and transition metals and their salts. Journal of the Chemical Society, Dalton Transactions. https://doi.org/10.1039/dt9850000307
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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