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Kinetics of activated chemisorption. Part 2.—Theoretical models
Abstract
In activated chemisorption the plot of the reciprocal of the rate Z=(dq/dt)–1 against the time t is convex towards the Z axis at low t and concave at high t. This condition is satisfied if both the energy of activation, Et and the number of available sites, Nt decrease with the coverage q and if d2Et/dq2 < 0. Two models are considered:
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Cited by
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Aljeboree, A. M., Alshirifi, A. N., & Alkaim, A. F. (2017) · Arabian Journal of Chemistry · doi:10.1016/j.arabjc.2014.01.020 · Cited by 844
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Metadata
- Authors
- Aharoni, C., & Ungarish, M.
- Venue
- Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 1977
- Volume
- 73
- Issue
- 0
- Pages
- 456
- ISSN
- 0300-9599 (ISSN-L)
- OpenAlex
- W1985395746
- Cited by
- 541
- References
- 0
- FWCI
- 1.48
- Type
- journal article
- Language
- en
- Open access
- closed
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- Aharoni, C., & Ungarish, M. (1977). Kinetics of activated chemisorption. Part 2.—Theoretical models. Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases. https://doi.org/10.1039/f19777300456
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