The DOI matches its Crossref record.
The thermodynamics of solvation of ions. Part 2.—The enthalpy of hydration at 298.15 K
Abstract
So-called ‘absolute’ standard molar enthalpies of hydration of individual ions at 298.15 K have been obtained from the conventional data by means of the widely employed TATB extrathermodynamic assumption, i.e. that ΔhydH°[(C6H5)4As+]=ΔhydH°[(C6H5)4P+]=ΔhydH°[B(C6H5)–4]. This is possible by the evaluation of the standard molar enthalpies of hydration of salts involving the tetraphenyl ions with suitable counter-ions from their lattice enthalpies and heats of solution and appropriate combinations of these data. The resulting value of the standard molar enthalpy of hydration of the hydrogen ion, ΔhydH°[H+]=–1103 ± 7 kJ mol–1, agrees with the values obtained by other reliable methods. The values of ΔhydH° on this basis of numerous ions are tabulated.
Overview
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
Citations
Cited by
Sorted by citations
Thermodynamics of solvation of ions. Part 5.—Gibbs free energy of hydration at 298.15 K
Marcus, Y. (1991) · Journal of the Chemical Society Faraday Transactions · doi:10.1039/ft9918702995 · Cited by 2,226
Self-citationArtificial Organic Host Molecules for Anions
Schmidtchen, F. P., & Berger, M. (1997) · Chemical Reviews · doi:10.1021/cr9603845 · Cited by 1,789
Intercalation chemistry of graphite: alkali metal ions and beyond
Li, Y., Lu, Y., Adelhelm, P., Titirici, M., & Hu, Y.-S. (2019) · Chemical Society Reviews · doi:10.1039/c9cs00162j · Cited by 918
Marcus, Y. (1994) · Biophysical Chemistry · doi:10.1016/0301-4622(94)00051-4 · Cited by 832
Self-citationIon Solvation Thermodynamics from Simulation with a Polarizable Force Field
Grossfield, A. M., Ren, P. Y., & Ponder, J. W. (2003) · Journal of the American Chemical Society · doi:10.1021/ja037005r · Cited by 526
Metadata
- Authors
- Marcus, Y.
- Corresponding author
- Marcus, Yizhak
- ORCID
- Marcus, Yizhak
- Venue
- Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 1987
- Volume
- 83
- Issue
- 2
- Pages
- 339
- ISSN
- 0300-9599 (ISSN-L)
- OpenAlex
- W2017026866
- Cited by
- 247
- References
- 0
- Citations by year
- 2026: 17 · 2025: 7 · 2024: 6 · 2023: 7 · 2022: 7 · 2021: 7 · 2020: 8 · 2019: 10 · 2018: 16 · 2017: 10 · 2016: 14 · 2015: 8 · 2014: 13 · 2013: 8 · 2012: 9
- FWCI
- 2.16
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Journal of the Chemical Society Faraday Transactions 1 Physical Chemistry in Condensed Phases (publishedVersion)
- Topics
- Physical Sciences › Chemistry › Organic Chemistry › Chemical Thermodynamics and Molecular Structure
- Physical Sciences › Chemical Engineering › Fluid Flow and Transfer Processes › Thermodynamic properties of mixtures
- Physical Sciences › Chemical Engineering › Filtration and Separation › Chemical and Physical Properties in Aqueous Solutions
- Keywords
- ion hydration, hydration enthalpy, tetraphenylborate, tetraphenylphosphonium, lattice enthalpy, enthalpy of solution, solvation thermodynamics
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
