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Theory of self-assembly of hydrocarbon amphiphiles into micelles and bilayers
Abstract
A simple theory is developed that accounts for many of the observed physical properties of micelles, both globular and rod-like, and of bilayer vesicles composed of ionic or zwitterionic amphiphiles. The main point of departure from previous theories lies in the recognition and elucidation of the role of geometric constraints in self-assembly. The linking together of thermodynamics, interaction free energies and geometry results in a general framework which permits extension to more complicated self-assembly problems.
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Citations
Cited by
Ghosh, S. K., & Pal, T. (2007) · Chemical Reviews · doi:10.1021/cr0680282 · Cited by 2,782
Ordered mesoporous materials in catalysis
Taguchi, A., & Schüth, F. (2005) · Microporous and Mesoporous Materials · doi:10.1016/j.micromeso.2004.06.030 · Cited by 2,119
Ciesla, U., & Schüth, F. (1999) · Microporous and Mesoporous Materials · doi:10.1016/s1387-1811(98)00249-2 · Cited by 1,084
The present state of affairs with Hofmeister effects
Kunz, W., Lo Nostro, P., & Ninham, B. W. (2004) · Current Opinion in Colloid & Interface Science · doi:10.1016/j.cocis.2004.05.004 · Cited by 854
Self-citationMotornov, M., Roiter, Y., Tokarev, I., & Minko, S. (2010) · Progress in Polymer Science · doi:10.1016/j.progpolymsci.2009.10.004 · Cited by 773
Metadata
- Authors
- Israelachvili, J. N., Mitchell, D. J., & Ninham, B. W.
- Venue
- Journal of the Chemical Society, Faraday Transactions 2
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 1976
- Volume
- 72
- Pages
- 1525
- ISSN
- 0300-9238 (ISSN-L)
- OpenAlex
- W2000966264
- Cited by
- 5,205
- References
- 0
- FWCI
- 13.94
- Type
- journal article
- Language
- en
- Open access
- closed
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- Israelachvili, J. N., Mitchell, D. J., & Ninham, B. W. (1976). Theory of self-assembly of hydrocarbon amphiphiles into micelles and bilayers. Journal of the Chemical Society, Faraday Transactions 2. https://doi.org/10.1039/f29767201525
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Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
