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Dynamics of concentrated polymer systems. Part 1.—Brownian motion in the equilibrium state
Abstract
In this series of papers, the dynamics of polymers in melts and concentrated solutions are discussed with the eventual aim of constructing the rheological constitutive equation. The basic ideas are introduced in this paper. A mathematical model chain which describes the motion of the polymer in the fully entangled state is presented and its Brownian motion in equilibrium is studied. The model chain, called the primitive chain, shows much qualitatively different behaviour from that of the Rouse chain used in dilute solution theory.
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Citations
Cited by
Dynamics of entangled linear polymer melts: A molecular-dynamics simulation
Kremer, K., & Grest, G. S. (1990) · The Journal of Chemical Physics · doi:10.1063/1.458541 · Cited by 4,023
The effect of entanglements in rubber elasticity
Edwards, S. F., & Vilgis, T. (1986) · Polymer · doi:10.1016/0032-3861(86)90231-4 · Cited by 460
Self-citationThe tube model theory of rubber elasticity
Edwards, S. F., & Vilgis, T. A. (1988) · Reports on Progress in Physics · doi:10.1088/0034-4885/51/2/003 · Cited by 384
Self-citationExplanation for the 3. 4-power law for viscosity of polymeric liquids on the basis of the tube model
Doi, M. (1983) · Journal of Polymer Science: Polymer Physics Edition · doi:10.1002/pol.1983.180210501 · Cited by 369
Self-citationDynamics of polymer solutions and melts. Reptation predictions and scaling of relaxation times
Paul, W., Binder, K., Heermann, D. W., & Kremer, K. (1991) · The Journal of Chemical Physics · doi:10.1063/1.461346 · Cited by 318
Metadata
- Authors
- Doi, M., & Edwards, S. F.
- Venue
- J. Chem. Soc., Faraday Trans. 2
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 1978
- Volume
- 74
- Issue
- 0
- Pages
- 1789-1801
- ISSN
- 0300-9238 (ISSN-L)
- OpenAlex
- W2075831361
- Cited by
- 1,379
- References
- 0
- FWCI
- 33.98
- Type
- journal article
- Language
- en
- Open access
- closed
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- Doi, M., & Edwards, S. F. (1978). Dynamics of concentrated polymer systems. Part 1.—Brownian motion in the equilibrium state. J. Chem. Soc., Faraday Trans. 2. https://doi.org/10.1039/f29787401789
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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