The DOI matches its Crossref record.
The kinetics and mechanism of the oxidation of amines and alcohols at oxide-covered nickel, silver, copper, and cobalt electrodes
Abstract
A series of alcohols and amines have been oxidised at oxide-covered nickel, silver, copper, and cobalt anodes in aqueous alkaline solutions. The kinetics of these electrode processes have been studied and it is shown that the mechanism of these oxidations involves hydrogen abstraction from the substrate by an oxide species rather than direct electron transfer to the anode. The mechanism put forward is compared with those commonly suggested for the chemical reactions of transition-metal oxides and for heterogeneous catalysis.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cited by
Proton-coupled electron transfer
Huynh, M. H. V., & Meyer, T. J. (2007) · Chemical Reviews · doi:10.1021/cr0500030 · Cited by 1,659
Non-enzymatic electrochemical sensing of glucose
Wang, G., He, X., Wang, L., Gu, A., Huang, Y., Fang, B., Geng, B., & Zhang, X. (2013) · Microchimica Acta · doi:10.1007/s00604-012-0923-1 · Cited by 522
Electrocatalytic Oxidation of 5‐(Hydroxymethyl)furfural Using High‐Surface‐Area Nickel Boride
Barwe, S., Weidner, J., Cychy, S., Morales, D. M., Dieckhöfer, S., Hiltrop, D., Masa, J., Muhler, M., & Schuhmann, W. (2018) · Angewandte Chemie International Edition · doi:10.1002/anie.201806298 · Cited by 507
Unraveling Two Pathways for Electrochemical Alcohol and Aldehyde Oxidation on NiOOH
Bender, M. T., Lam, Y. C., Hammes-Schiffer, S., & Choi, K.-S. (2020) · Journal of the American Chemical Society · doi:10.1021/jacs.0c10924 · Cited by 409
Direct urea fuel cells: Challenges and opportunities
Sayed, E. T., Eisa, T., Mohamed, H. O., Abdelkareem, M. A., Allagui, A., Alawadhi, H., & Chae, K.-J. (2019) · Journal of Power Sources · doi:10.1016/j.jpowsour.2018.12.024 · Cited by 322
Metadata
- Authors
- Fleischmann, M., Korinek, K., & Pletcher, D.
- Venue
- Journal of the Chemical Society, Perkin Transactions 2
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 1972
- Issue
- 10
- Pages
- 1396
- ISSN
- 0300-9580 (ISSN-L)
- 1364-5471
- OpenAlex
- W2013738735
- Cited by
- 460
- References
- 0
- FWCI
- 2.22
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
How to cite
Cite CoChat for the checks on this page, and the paper for its own findings.
- This page
- CoChat. (2026). Citation check: The kinetics and mechanism of the oxidation of amines and alcohols at oxide-covered nickel, silver, copper, and cobalt electrodes. https://app.cochat.ai/papers/10.1039/p29720001396
- The paper
- Fleischmann, M., Korinek, K., & Pletcher, D. (1972). The kinetics and mechanism of the oxidation of amines and alcohols at oxide-covered nickel, silver, copper, and cobalt electrodes. Journal of the Chemical Society, Perkin Transactions 2. https://doi.org/10.1039/p29720001396
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
