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The structure of ribonucleic acids. 1. Cyclic nucleotides produced by ribonuclease and by alkaline hydrolysis
Open accessAbstract
em^.. If, however, a similar compound is obtained from a reaction mixture containing the C2OH260 compound its properties suggest C25H340, i.e. it derives from the C2oH260 compound.SUMMARY 1. Oppenauer oxidation of vitamin A using diethyl ketone as hydrogen acceptor results in a complex mixture from which a compound C2OH260 (isomeric with retinene2) can be isolated.It gives an oxime, m.p. 175177o, isolated by previous workers.2. The C20H260 compound, is reducible in vitro and in vivo, but the product differs from vitamin A2.3. The Oppenauer oxidation seems to proceed via retinenel, C20H280, which can either be further dehydrogenated to C20H,60 or can condense with diethyl ketone, to a ketone C25H360.Condensationof the C20H260 compound with diethyl ketone to yield C2,H..O is not excluded.4. Vitamin A acetate is not dehydrogenated directly to vitamin A2.
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Citations
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Theoretical basis for stabilizing messenger RNA through secondary structure design
Wayment-Steele, H. K., Kim, D. S., Choe, C. A., Nicol, J. J., Wellington-Oguri, R., Watkins, A. M., Sperberg, R. A. P., Huang, P.-S., Participants, E., & Das, R. (2020) · doi:10.1101/2020.08.22.262931 · Cited by 199
Metadata
- Authors
- Markham, R., & Smith, J. D.
- Venue
- Biochemical Journal
- Publisher
- Portland Press Ltd.
- Published
- 1952-12-01
- Volume
- 52
- Issue
- 4
- Pages
- 552-557
- ISSN
- 0306-3283 (ISSN-L)
- OpenAlex
- W2256273377
- Cited by
- 779
- References
- 0
- FWCI
- 20.73
- Type
- journal article
- Language
- en
- Open access
- bronze
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- Markham, R., & Smith, J. D. (1952). The structure of ribonucleic acids. 1. Cyclic nucleotides produced by ribonuclease and by alkaline hydrolysis. Biochemical Journal. https://doi.org/10.1042/bj0520552
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