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Cited by 411

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Synthesis and physical-chemical properties of ionic liquids based on 1-n-butyl-3-methylimidazolium cation

Suarez, P. A.Z., Einloft, S., Dullius, J. E.L., de Souza, R. F., Dupont, J.·1998·Journal de Chimie Physique et de Physico-Chimie Biologique
DOI 10.1051/jcp:1998103
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Abstract

The reaction of 1-n-butyl-3-methylimidazolium chloride (BMI.Cl) with sodium tetrafluoroborate or sodium hexafluorophosphate affords the molten salts BMI.X (1, X= BF4 and 2, X= PF6). Compounds 1 and 2 are viscous liquids within a wide range of temperature (down to 192 K). IR, NMR, density, viscosity and conductivity measurements suggest that compound 2 behaves quasi-molecular. Compound 1 is quasi-molecular below 279 K, but at higher temperatures is probably composed of imidazolium and tetrafluoroborate ions in an extended hydrogen-bonded network.

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Metadata

Authors
Suarez, P. A. Z., Einloft, S., Dullius, J. E. L., de Souza, R. F., & Dupont, J.
Venue
Journal de Chimie Physique et de Physico-Chimie Biologique
Publisher
EDP Sciences
Published
1998-07
Volume
95
Issue
7
Pages
1626-1639
ISSN
0021-7689 (ISSN-L)
DOI
10.1051/jcp:1998103
OpenAlex
W2058670733
Cited by
411
References
0
FWCI
4.02
Type
journal article
Language
fr
Open access
closed

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CoChat. (2026). Citation check: Synthesis and physical-chemical properties of ionic liquids based on 1-n-butyl-3-methylimidazolium cation. https://app.cochat.ai/papers/10.1051/jcp:1998103
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Suarez, P. A. Z., Einloft, S., Dullius, J. E. L., de Souza, R. F., & Dupont, J. (1998). Synthesis and physical-chemical properties of ionic liquids based on 1-n-butyl-3-methylimidazolium cation. Journal de Chimie Physique et de Physico-Chimie Biologique. https://doi.org/10.1051/jcp%3A1998103

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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).

Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.