The DOI matches its Crossref record; 8 of the 8 references it cites were found in a registry or an index.
Statistics of macromolecular solutions trapped in small pores
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Résumé. 2014 Nous analysons le comportement de solutions en bon solvant de chaines macro-moléculaires et confinées dans des tubes (ou des lamelles) de diamètre D comparable au rayon de la pelote. Les interactions répulsives entre monomères sont prises en compte grâce à une méthode d’échelle qui va au-delà de la théorie usuelle de Flory-Huggins. Pour le problème des lamelles, nous trouvons cinq régimes différents (dépendant de la concen-tration C et du diamètre D) avec des changements de comportement réguliers à toutes les frontières. Dans le problème des tubes un de ces régimes disparait et deux lignes de cross-over se confondent, donnant lieu à une discontinuité plus marquée. Ceci est lié au fait que lorsque D devient de l’ordre de la taille du monomère, les différentes pelotes ne peuvent plus s’interpénétrer. Les propriétés thermodynamiques, les corrélations locales et la taille de la chaine sont estimées dans chaque cas. Toutefois les arguments d’échelle prédisent seulement les lois de puissance (en C et D) pour toutes ces quantités mais ne donnent pas les coefficients numériques. Abstract. 2014 We analyse the theoretical behaviour of macromolecular chains dissolved in a good solvent, and confined into tubes (or slits) of diameter D comparable to the coil radius. The repulsive interactions between monomers are taken into account by a scaling method which goes beyond the
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Cites
Principles of polymer chemistry
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Scaling Theory for Finite-Size Effects in the Critical Region
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Edwards, S. F. (1965) · Proceedings of the Physical Society · doi:10.1088/0370-1328/85/4/301 · Cited by 1,355
Solutions of Flexible Polymers. Neutron Experiments and Interpretation
Daoud, M., Cotton, J. P., Farnoux, B., Jannink, G., Sarma, G., Benoit, H. C., Duplessix, C., Picot, C., & de Gennes, P. G. (1975) · Macromolecules · doi:10.1021/ma60048a024 · Cited by 908
Self-citationDynamics of Entangled Polymer Solutions. I. The Rouse Model
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Mathematical physics in one dimension
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Diffusion and partitioning of macromolecules within finely porous glass
Colton, C. K., Satterfield, C. N., & Lai, C. S. (1975) · AIChE Journal · doi:10.1002/aic.690210210 · Cited by 102
Cited by
Dynamics of polymer chains confined into tubes: Scaling theory and Monte Carlo simulations
Kremer, K., & Binder, K. (1984) · The Journal of Chemical Physics · doi:10.1063/1.447549 · Cited by 130
Breton, M. F., Discala, F., Bacri, L., Foster, D., Pelta, J., & Oukhaled, A. (2013) · The Journal of Physical Chemistry Letters · doi:10.1021/jz400938q · Cited by 63
Metadata
- Authors
- Daoud, M., & De Gennes, P. G.
- Venue
- Journal de Physique
- Publisher
- EDP Sciences
- Published
- 1977
- Volume
- 38
- Issue
- 1
- Pages
- 85-93
- ISSN
- 0302-0738 (ISSN-L)
- OpenAlex
- W2021767200
- Cited by
- 561
- References
- 8
- FWCI
- 5.69
- Type
- journal article
- Language
- fr
- Open access
- green
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