The DOI matches its Crossref record.
The Use of Diethyl Azodicarboxylate and Triphenylphosphine in Synthesis and Transformation of Natural Products
Abstract
Abstract The reagent formed by combining diethyl azodicarboxylate (DEAD) and triphenylphosphine (TPP) could be utilized in the intermolecular dehydration between an alcohol and various acidic components such as carboxylic acids, phosphoric diesters, imides, and active methylene compounds. By the use of DEAD and TPP, diols and hydroxy acids gave cyclic ethers and lactones, respectively. The reaction of nucleosides with DEAD and TPP afforded triphenylphosphoranylnucleosides. Alcohols reacted with 2,6-di-t-butyl-4-nitrophenol in the presence of DEAD and TPP to give aci-nitroesters which converted into the corresponding carbonyl compounds.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cited by
Chemical Routes for the Transformation of Biomass into Chemicals
Corma, A., Iborra, S., & Velty, A. (2007) · Chemical Reviews · doi:10.1021/cr050989d · Cited by 5,970
On the Trail of Xanthates: Some New Chemistry from an Old Functional Group
Zard, S. Z. (1997) · Angewandte Chemie International Edition in English · doi:10.1002/anie.199706721 · Cited by 444
Martin, S. F., & Dodge, J. A. (1991) · Tetrahedron Letters · doi:10.1016/0040-4039(91)80675-v · Cited by 357
Yang, Z., Hutter, D., Sheng, P., Sismour, A. M., & Benner, S. A. (2006) · Nucleic Acids Research · doi:10.1093/nar/gkl633 · Cited by 196
Fluorous phase chemistry: a new industrial technology
Dobbs, A. P., & Kimberley, M. R. (2002) · Journal of Fluorine Chemistry · doi:10.1016/s0022-1139(02)00202-6 · Cited by 131
Metadata
- Authors
- Mitsunobu, O.
- Venue
- Synthesis
- Publisher
- Georg Thieme Verlag KG
- Published
- 1981
- Volume
- 1981
- Issue
- 01
- Pages
- 1-28
- ISSN
- 0039-7881 (ISSN-L)
- 1437-210X
- OpenAlex
- W233628489
- Cited by
- 4,118
- References
- 0
- FWCI
- 35.73
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
How to cite
Cite CoChat for the checks on this page, and the paper for its own findings.
- This page
- CoChat. (2026). Citation check: The Use of Diethyl Azodicarboxylate and Triphenylphosphine in Synthesis and Transformation of Natural Products. https://app.cochat.ai/papers/10.1055/s-1981-29317
- The paper
- Mitsunobu, O. (1981). The Use of Diethyl Azodicarboxylate and Triphenylphosphine in Synthesis and Transformation of Natural Products. Synthesis. https://doi.org/10.1055/s-1981-29317
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
