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Semiconducting polymer-buckminsterfullerene heterojunctions: Diodes, photodiodes, and photovoltaic cells
Abstract
The characterization of rectifying heterojunctions (diodes) fabricated from a semiconducting polymer, a soluble derivative of poly(phenylene-vinylene), and buckminsterfullerene, C60, are reported. Rectification ratios in the current versus voltage characteristics exceed 104. When illuminated, the devices exhibit a large photoresponse as a result of photoinduced electron transfer across the heterojunction interface from the semiconducting polymer (donor) onto C60 (acceptor). The photodiode and photovoltaic responses are characterized. Photoinduced electron transfer across the donor-accepted rectifying heterojunction offers potential for photodetector and for solar cell applications.
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Citations
Cited by
Conjugated Polymer-Based Organic Solar Cells
Günes, S., Neugebauer, H., & Sariciftci, N. S. (2007) · Chemical Reviews · doi:10.1021/cr050149z · Cited by 6,279
Moliton, A., & Hiorns, R. C. (2004) · Polymer International · doi:10.1002/pi.1587 · Cited by 409
Umeyama, T., Takamatsu, T., Tezuka, N., Matano, Y., Araki, Y., Wada, T., Yoshikawa, O., Sagawa, T., Yoshikawa, S., & Imahori, H. (2009) · The Journal of Physical Chemistry C · doi:10.1021/jp902001z · Cited by 119
Metadata
- Authors
- Sariciftci, N. S., Braun, D., Zhang, C., Srdanov, V. I., Heeger, A. J., Stucky, G., & Wudl, F.
- Venue
- Applied Physics Letters
- Publisher
- AIP Publishing
- Published
- 1993-02-08
- Volume
- 62
- Issue
- 6
- Pages
- 585-587
- ISSN
- 0003-6951 (ISSN-L)
- 1077-3118
- OpenAlex
- W2011292091
- Cited by
- 961
- References
- 0
- FWCI
- 38.50
- Type
- journal article
- Language
- en
- Open access
- closed
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