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A monoclinic ferroelectric phase in the Pb(Zr1−xTix)O3 solid solution
Open accessAbstract
A previously unreported ferroelectric phase has been discovered in a highly homogeneous sample of PbZr0.52Ti0.48O3 by high-resolution synchrotron x-ray powder diffraction measurements. At ambient temperature the sample has tetragonal symmetry (at=4.037 Å, ct=4.138 Å), and transforms below ∼250 K into a phase which, unexpectedly, has monoclinic symmetry (am=5.717 Å, bm=5.703 Å, cm=4.143 Å, β=90.53°, at 20 K). The intensity data strongly indicate that the polar axis lies in the monoclinic ac plane close to the pseudocubic [111] direction, which would be an example of the species m3m(12)A2Fm predicted on symmetry grounds by Shuvalov.
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Cited by
Origin of morphotropic phase boundaries in ferroelectrics
Ahart, M., Somayazulu, M., Cohen, R. E., Ganesh, P., Dera, P., Mao, H.-K., Hemley, R. J., Ren, Y., Liermann, P., & Wu, Z. (2008) · Nature · doi:10.1038/nature06459 · Cited by 914
Contributions to the piezoelectric effect in ferroelectric single crystals and ceramics
Damjanovic, D. (2005) · Journal of the American Ceramic Society · doi:10.1111/j.1551-2916.2005.00671.x · Cited by 708
Structure and high-piezoelectricity in lead oxide solid solutions
Noheda, B. (2002) · Current Opinion in Solid State and Materials Science · doi:10.1016/s1359-0286(02)00015-3 · Cited by 448
Self-citationPramanick, A., Damjanovic, D., Nino, J. C., & Jones, J. L. (2009) · Journal of the American Ceramic Society · doi:10.1111/j.1551-2916.2009.03218.x · Cited by 80
Metadata
- Authors
- Noheda, B., Cox, D. E., Shirane, G., Gonzalo, J. A., Cross, L. E., & Park, S.-E.
- Venue
- Applied Physics Letters
- Publisher
- AIP Publishing
- Published
- 1999-04-05
- Volume
- 74
- Issue
- 14
- Pages
- 2059-2061
- ISSN
- 0003-6951 (ISSN-L)
- 1077-3118
- OpenAlex
- W2122913384
- Cited by
- 1,070
- References
- 0
- FWCI
- 21.16
- Type
- journal article
- Language
- en
- Open access
- green
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- Noheda, B., Cox, D. E., Shirane, G., Gonzalo, J. A., Cross, L. E., & Park, S.-E. (1999). A monoclinic ferroelectric phase in the Pb(Zr1−xTix)O3 solid solution. Applied Physics Letters. https://doi.org/10.1063/1.123756
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