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Hydrogen adsorption and cohesive energy of single-walled carbon nanotubes
Open accessAbstract
Hydrogen adsorption on crystalline ropes of carbon single-walled nanotubes (SWNT) was found to exceed 8 wt. %, which is the highest capacity of any carbon material. Hydrogen is first adsorbed on the outer surfaces of the crystalline ropes. At pressures higher than about 40 bar at 80 K, however, a phase transition occurs where there is a separation of the individual SWNTs, and hydrogen is physisorbed on their exposed surfaces. The pressure of this phase transition provides a tube-tube cohesive energy for much of the material of 5 meV/C atom. This small cohesive energy is affected strongly by the quality of crystalline order in the ropes.
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Cited by
Donaldson, K., Aitken, R., Tran, L., Stone, V., Duffin, R., Forrest, G., & Alexander, A. (2006) · Toxicological Sciences · doi:10.1093/toxsci/kfj130 · Cited by 1,167
Gas molecule adsorption in carbon nanotubes and nanotube bundles
Zhao, J., Buldum, A., Han, J., & Lu, J. P. (2002) · Nanotechnology · doi:10.1088/0957-4484/13/2/312 · Cited by 1,163
Pillared Graphene: A New 3-D Network Nanostructure for Enhanced Hydrogen Storage
Dimitrakakis, G. K., Tylianakis, E., & Froudakis, G. E. (2008) · Nano Letters · doi:10.1021/nl801417w · Cited by 772
Progress and problems in hydrogen storage methods
Zhou, L. (2005) · Renewable and Sustainable Energy Reviews · doi:10.1016/j.rser.2004.05.005 · Cited by 691
A review: Hydrogen generation from borohydride hydrolysis reaction
Liu, B. H., & Li, Z. P. (2009) · Journal of Power Sources · doi:10.1016/j.jpowsour.2008.11.032 · Cited by 573
Metadata
- Authors
- Ye, Y., Ahn, C. C., Witham, C., Fultz, B., Liu, J., Rinzler, A. G., Colbert, D., Smith, K. A., & Smalley, R. E.
- Venue
- Applied Physics Letters
- Publisher
- AIP Publishing
- Published
- 1999-04-19
- Volume
- 74
- Issue
- 16
- Pages
- 2307-2309
- ISSN
- 0003-6951 (ISSN-L)
- 1077-3118
- OpenAlex
- W2137042069
- Cited by
- 904
- References
- 0
- FWCI
- 44.32
- Type
- journal article
- Language
- en
- Open access
- bronze
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- Ye, Y., Ahn, C. C., Witham, C., Fultz, B., Liu, J., Rinzler, A. G., Colbert, D., Smith, K. A., & Smalley, R. E. (1999). Hydrogen adsorption and cohesive energy of single-walled carbon nanotubes. Applied Physics Letters. https://doi.org/10.1063/1.123833
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
