The DOI matches its Crossref record; 55 of the 55 references it cites were found in a registry or an index.
New insights into the fragility dilemma in liquids
Abstract
A compilation of data for small molecule organic, polymeric, and inorganic glass-forming liquids shows that the original expectation, that there be a positive correlation between the thermodynamic measure of fragility Cpl/Cpg (or Cpl/Cpc) and the dynamic fragility index m, is not generally true. The results are consistent with three classes of behavior: (1) a decrease in m with increasing Cpl/Cpg for the polymeric glass formers; (2) a nearly constant value of m independent of Cpl/Cpc for small molecule organics and hydrogen bonding small molecules; (3) an increasing value of m with increasing Cpl/Cpc for inorganic glass formers as originally considered by Angell.
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Cites
Data Reduction and Error Analysis for the Physical Sciences
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Viscoelastic Properties of Polymers
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On the Temperature Dependence of Cooperative Relaxation Properties in Glass-Forming Liquids
Adam, G., & Gibbs, J. H. (1965) · The Journal of Chemical Physics · doi:10.1063/1.1696442 · Cited by 5,836
Formation of Glasses from Liquids and Biopolymers
Angell, C. A. (1995) · Science · doi:10.1126/science.267.5206.1924 · Cited by 4,799
ANALYSIS OF RECENT MEASUREMENTS OF THE VISCOSITY OF GLASSES
Fulcher, G. S. (1925) · Journal of the American Ceramic Society · doi:10.1111/j.1151-2916.1925.tb16731.x · Cited by 4,181
Die Abhängigkeit der Viscosität von der Temperatur bie unterkühlten Flüssigkeiten
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Nonexponential relaxations in strong and fragile glass formers
Böhmer, R., Ngai, K. L., Angell, C. A., & Plazek, D. J. (1993) · The Journal of Chemical Physics · doi:10.1063/1.466117 · Cited by 2,412
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Dielectric Relaxation in Glycerol, Propylene Glycol, and n-Propanol
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Cited by
Molecular-weight dependence of enthalpy relaxation of PMMA
Andreozzi, L., Faetti, M., Giordano, M., & Zulli, F. (2005) · Macromolecules · doi:10.1021/ma0507037 · Cited by 74
Metadata
- Authors
- Huang, D., & McKenna, G. B.
- Venue
- The Journal of Chemical Physics
- Publisher
- AIP Publishing
- Published
- 2001-04-01
- Volume
- 114
- Issue
- 13
- Pages
- 5621-5630
- ISSN
- 0021-9606 (ISSN-L)
- 1089-7690
- OpenAlex
- W1988694571
- Cited by
- 310
- References
- 55
- FWCI
- 8.36
- Type
- journal article
- Language
- en
- Open access
- closed
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