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Structure and electrostatic properties of passivated CdSe nanocrystals
Abstract
The electrostatic and structural properties of CdSe nanocrystals are discussed using an atomistic model that treats both the nanocrystal core and its passivation layer. The model predicts the presence of a permanent dipole moment for CdSe nanocrystals in the wurtzite crystal structure. The dipole moment is mildly screened by the nanocrystal’s passivation layer, and is significantly reduced due to surface reconstruction and relaxation. Possible explanation for preferential growth of CdSe particles along the c-axis is provided with a detailed analysis of the structural reconstruction of the different surfaces.
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Cites
Shape control of CdSe nanocrystals
Peng, X., Manna, L., Yang, W., Wickham, J., Scher, E., Kadavanich, A., & Alivisatos, A. P. (2000) · Nature · doi:10.1038/35003535 · Cited by 4,487
Cited by
Size dependence of nanostructures: Impact of bond order deficiency
Sun, C. Q. (2007) · Progress in Solid State Chemistry · doi:10.1016/j.progsolidstchem.2006.03.001 · Cited by 873
Self-Assembly of Patchy Particles
Zhang, Z., & Glotzer, S. C. (2004) · Nano Letters · doi:10.1021/nl0493500 · Cited by 819
One‐Dimensional Assemblies of Nanoparticles: Preparation, Properties, and Promise
Tang, Z., & Kotov, N. A. (2005) · Advanced Materials · doi:10.1002/adma.200401593 · Cited by 770
Nanoparticles: Strained and Stiff
Gilbert, B., Huang, F., Zhang, H., Waychunas, G. A., & Banfield, J. F. (2004) · Science · doi:10.1126/science.1098454 · Cited by 472
Xu, X., Zhuang, J., & Wang, X. (2008) · Journal of the American Chemical Society · doi:10.1021/ja8040527 · Cited by 408
Metadata
- Authors
- Rabani, E.
- Venue
- The Journal of Chemical Physics
- Publisher
- AIP Publishing
- Published
- 2001-07-15
- Volume
- 115
- Issue
- 3
- Pages
- 1493-1497
- ISSN
- 0021-9606 (ISSN-L)
- 1089-7690
- OpenAlex
- W2147310204
- Cited by
- 167
- References
- 1
- FWCI
- 4.58
- Type
- journal article
- Language
- en
- Open access
- closed
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