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Surface plasmon broadening for arbitrary shape nanoparticles: A geometrical probability approach
Abstract
A geometrical probability measure is proposed for calculating the effective conduction electron mean free path of an arbitrary shape convex particle. It is shown that the plasmon widths determined from this mean free path are consistent with exact quantum mechanical widths for simple particle shapes. We use the mean free path formula to evaluate size and shape dependent dielectric functions and extinction spectra for silver spheroids, square prisms, truncated tetrahedrons, and cylinders.
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Citations
Cited by
Hu, M., Novo, C., Funston, A., Wang, H., Staleva, H., Zou, S., Mulvaney, P., Xia, Y., & Hartland, G. V. (2008) · Journal of Materials Chemistry · doi:10.1039/b714759g · Cited by 508
Theoretical Studies of Plasmonics using Electronic Structure Methods
Morton, S. M., Silverstein, D. W., & Jensen, L. (2011) · Chemical Reviews · doi:10.1021/cr100265f · Cited by 474
Synthesis and Optical Characterization of Au/Ag Core/Shell Nanorods
Liu, & Guyot-Sionnest, P. (2004) · The Journal of Physical Chemistry B · doi:10.1021/jp037644o · Cited by 448
Synthesis and Optical Properties of Anisotropic Metal Nanoparticles
Hao, E., Schatz, G. C., & Hupp, J. T. (2004) · Journal of Fluorescence · doi:10.1023/b:jofl.0000031815.71450.74 · Cited by 312
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Metadata
- Authors
- Coronado, E. A., & Schatz, G. C.
- Venue
- The Journal of Chemical Physics
- Publisher
- AIP Publishing
- Published
- 2003-08-15
- Volume
- 119
- Issue
- 7
- Pages
- 3926-3934
- ISSN
- 0021-9606 (ISSN-L)
- 1089-7690
- OpenAlex
- W2084250200
- Cited by
- 439
- References
- 0
- FWCI
- 9.48
- Type
- journal article
- Language
- en
- Open access
- closed
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- Coronado, E. A., & Schatz, G. C. (2003). Surface plasmon broadening for arbitrary shape nanoparticles: A geometrical probability approach. The Journal of Chemical Physics. https://doi.org/10.1063/1.1587686
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