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Electrochemical properties of carbon nanofiber web as an electrode for supercapacitor prepared by electrospinning
Abstract
Poly(acrylonitrile) solutions in dimethylformamide were electrospun to be webs consisting of 300 nm ultrafine fibers. The webs were oxidatively stabilized and activated by steam resulting in activated carbon nanofibers (ACNFs). The specific surface area of the ACNF activated at 700 °C was the highest but mesopore volume fraction of that was lowest. On the other hand, the ACNFs activated at 800 °C showed opposite trends to those activated at 700 °C. The high specific surface area, mainly due to the micropores, introduced maximum specific capacitance at low current density (173 F/g at 10 mA/g). The elevated volume fraction of mesopores gave maximum specific capacitance at high current density (120 F/g at 1000 mA/g). The behavior is explained on the basis of ion mobility in the pores.
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Cited by
Energy storage in electrochemical capacitors: designing functional materials to improve performance
Hall, P. J., Mirzaeian, M., Fletcher, S. I., Sillars, F. B., Rennie, A. J. R., Shitta-Bey, G. O., Wilson, G., Cruden, A., & Carter, R. (2010) · Energy & Environmental Science · doi:10.1039/c0ee00004c · Cited by 1,162
Electrospun nanofiber reinforced composites: a review
Jiang, S., Chen, Y., Duan, G., Mei, C., Greiner, A., & Agarwal, S. (2018) · Polymer Chemistry · doi:10.1039/c8py00378e · Cited by 560
Nanowires for Electrochemical Energy Storage
Zhou, G., Xu, L., Hu, G., Mai, L., & Cui, Y. (2019) · Chemical Reviews · doi:10.1021/acs.chemrev.9b00326 · Cited by 439
Lu, X., Wang, C., Favier, F., & Pinna, N. (2017) · Advanced Energy Materials · doi:10.1002/aenm.201601301 · Cited by 429
Magnetic‐Field‐Assisted Electrospinning of Aligned Straight and Wavy Polymeric Nanofibers
Liu, Y., Zhang, X., Xia, Y., & Yang, H. (2010) · Advanced Materials · doi:10.1002/adma.200903870 · Cited by 261
Metadata
- Authors
- Kim, C., & Yang, K. S.
- Venue
- Applied Physics Letters
- Publisher
- AIP Publishing
- Published
- 2003-08-11
- Volume
- 83
- Issue
- 6
- Pages
- 1216-1218
- ISSN
- 0003-6951 (ISSN-L)
- 1077-3118
- OpenAlex
- W2058971825
- Cited by
- 496
- References
- 0
- FWCI
- 7.34
- Type
- journal article
- Language
- en
- Open access
- closed
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