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Protonic Conductivity in Imidazole Single Crystal
Abstract
Imidazole single crystal has a highly anisotropic conductivity; the ratio of conductivity in the c and a crystallographic directions is ∼103. In the c crystallographic direction, the hydrogen bonded direction, protonic carriers are discharged as hydrogen at the negative electrode. The limiting conduction process is possibly due to L-defect injection and transport back down the hydrogen bonded chain after the proton is discharged. Conductivity in the a direction is probably electronic and extrinsic.
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Citations
Cited by
Kreuer, K.-D., Paddison, S. J., Spohr, E., & Schuster, M. (2004) · Chemical Reviews · doi:10.1021/cr020715f · Cited by 2,187
On the development of proton conducting materials for technological applications
Kreuer, K. D. (1997) · Solid State Ionics · doi:10.1016/s0167-2738(97)00082-9 · Cited by 1,036
Proton conduction in crystalline and porous covalent organic frameworks
Xu, H., Tao, S., & Jiang, D. (2016) · Nature Materials · doi:10.1038/nmat4611 · Cited by 782
Proton Transport in Metal–Organic Frameworks
Lim, D.-W., & Kitagawa, H. (2020) · Chemical Reviews · doi:10.1021/acs.chemrev.9b00842 · Cited by 689
Hydrogen bonded chain mechanisms for proton conduction and proton pumping
Nagle, J. F., & Tristram-Nagle, S. (1983) · The Journal of Membrane Biology · doi:10.1007/bf01870590 · Cited by 393
Metadata
- Authors
- Kawada, A., McGhie, A. R., & Labes, M. M.
- Venue
- The Journal of Chemical Physics
- Publisher
- AIP Publishing
- Published
- 1970-03-15
- Volume
- 52
- Issue
- 6
- Pages
- 3121-3125
- ISSN
- 0021-9606 (ISSN-L)
- 1089-7690
- OpenAlex
- W2031232847
- Cited by
- 204
- References
- 0
- FWCI
- 4.25
- Type
- journal article
- Language
- en
- Open access
- closed
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- CoChat. (2026). Citation check: Protonic Conductivity in Imidazole Single Crystal. https://app.cochat.ai/papers/10.1063/1.1673447
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- Kawada, A., McGhie, A. R., & Labes, M. M. (1970). Protonic Conductivity in Imidazole Single Crystal. The Journal of Chemical Physics. https://doi.org/10.1063/1.1673447
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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