The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
Use of X-Ray Photoelectron Spectroscopy to Study Bonding in Cr, Mn, Fe, and Co Compounds
Abstract
The photoelectron spectra of some 40 transition metal compounds have been measured using AlKα(1487 eV) and MgKα(1254 eV) x-rays. The compounds included both simple salts (halides and chalcogenides) and hexacoordinated complexes (cyano- and fluoro-) of Cr(III), Mn(II, III), Fe(II, III), and Co(III). From these data we have determined the chemical shifts of the core electrons and related these results to a calculated charge based on Pauling's electronegativities. In addition, multiplet splitting has been obtained for photoionization in the 3s shell and is discussed in terms of the exchange interaction between the partially filled 3s and 3d orbitals. To help in this explanation, calculations were made using both (1) Hartree-Fock solutions of the wavefunctions for free ions and (2) a qualitative evaluation of the behavior of the exchange integral. The value of using x-ray photoelectron spectroscopy for studying chemical bonding for transition metal compounds is amply illustrated.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
(1999) · Choice Reviews Online · doi:10.5860/choice.37-0940 · Cited by 14,314
Cited by
Nesbitt, H. W., & Banerjee, D. (1998) · American Mineralogist · doi:10.2138/am-1998-3-414 · Cited by 1,207
Core–Shell Fe–Pt Nanoparticles in Ionic Liquids: Magnetic and Catalytic Properties
Adamski, J., Qadir, M. I., Serna, J. P., Bernardi, F., Baptista, D. L., Salles, B. R., Novak, M. A., Machado, G., & Dupont, J. (2018) · The Journal of Physical Chemistry C · doi:10.1021/acs.jpcc.7b12219 · Cited by 32
Metadata
- Authors
- Carver, J. C., Schweitzer, G. K., & Carlson, T. A.
- Venue
- The Journal of Chemical Physics
- Publisher
- AIP Publishing
- Published
- 1972-07-15
- Volume
- 57
- Issue
- 2
- Pages
- 973-982
- ISSN
- 0021-9606 (ISSN-L)
- 1089-7690
- OpenAlex
- W2060546198
- Cited by
- 712
- References
- 1
- FWCI
- 11.83
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
How to cite
Cite CoChat for the checks on this page, and the paper for its own findings.
- This page
- CoChat. (2026). Citation check: Use of X-Ray Photoelectron Spectroscopy to Study Bonding in Cr, Mn, Fe, and Co Compounds. https://app.cochat.ai/papers/10.1063/1.1678348
- The paper
- Carver, J. C., Schweitzer, G. K., & Carlson, T. A. (1972). Use of X-Ray Photoelectron Spectroscopy to Study Bonding in Cr, Mn, Fe, and Co Compounds. The Journal of Chemical Physics. https://doi.org/10.1063/1.1678348
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
