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On the Theory of Electron-Transfer Reactions. VI. Unified Treatment for Homogeneous and Electrode Reactions
Abstract
A unified theory of homogeneous and electrochemical electron-transfer rates is developed using statistical mechanics. The treatment is a generalization of earlier papers of this series and is concerned with seeking a fairly broad basis for the quantitative correlations among chemical and electrochemical rate constants predicted in these earlier papers. The atomic motions inside the inner coordination shell of each reactant are treated as vibrations. The motions outside are treated by the ``particle description,'' which emphasizes the functional dependence of potential energy and free energy on molecular properties and which avoids, thereby, some unnecessary assumptions about the molecular interactions.
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Citations
Cited by
Electron transfer reactions in chemistry. Theory and experiment
Marcus, R. A. (1993) · Reviews of Modern Physics · doi:10.1103/revmodphys.65.599 · Cited by 3,667
Self-citationFree Energy and Temperature Dependence of Electron Transfer at the Metal-Electrolyte Interface
Chidsey, C. E. D. (1991) · Science · doi:10.1126/science.251.4996.919 · Cited by 1,313
Tay, N. E. S., Lehnherr, D., & Rovis, T. (2022) · Chemical Reviews · doi:10.1021/acs.chemrev.1c00384 · Cited by 518
Quantum mechanical tunnelling in biological systems
Devault, D. (1980) · Quarterly Reviews of Biophysics · doi:10.1017/s003358350000175x · Cited by 406
Schoetz, T., Gordon, L. W., Ivanov, S., Bund, A., Mandler, D., & Messinger, R. J. (2022) · Electrochimica Acta · doi:10.1016/j.electacta.2022.140072 · Cited by 404
Metadata
- Authors
- Marcus, R. A.
- Venue
- The Journal of Chemical Physics
- Publisher
- AIP Publishing
- Published
- 1965-07-15
- Volume
- 43
- Issue
- 2
- Pages
- 679-701
- ISSN
- 0021-9606 (ISSN-L)
- 1089-7690
- OpenAlex
- W2008631597
- Cited by
- 2,789
- References
- 0
- FWCI
- 5.25
- Type
- journal article
- Language
- en
- Open access
- closed
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- Marcus, R. A. (1965). On the Theory of Electron-Transfer Reactions. VI. Unified Treatment for Homogeneous and Electrode Reactions. The Journal of Chemical Physics. https://doi.org/10.1063/1.1696792
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