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Molecular Motion in Infrared and Raman Spectra
Abstract
It is suggested that Fourier transformation of infrared and Raman band shapes reveals the meaning of the spectrum in terms of molecular rotation much more clearly than does the usual frequency shape. By looking at the time dependence directly, one may separately examine the molecular motion at short and long times The motion at short times may be analyzed directly in terms of the molecular dynamics, by the use of a power series in the time, whereas the behavior at long times is best examined by statistical arguments. This kind of analysis is illustrated by several examples, including the spectra of liquid CO and CH4.
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Citations
Cited by
Integrated Intensities of Absorption Bands in Infrared Spectroscopy
Wexler, A. S. (1967) · Applied Spectroscopy Reviews · doi:10.1080/05704926708547581 · Cited by 164
Metadata
- Authors
- Gordon, R. G.
- Venue
- The Journal of Chemical Physics
- Publisher
- AIP Publishing
- Published
- 1965-08-15
- Volume
- 43
- Issue
- 4
- Pages
- 1307-1312
- ISSN
- 0021-9606 (ISSN-L)
- 1089-7690
- OpenAlex
- W2008230286
- Cited by
- 605
- References
- 0
- FWCI
- 13.06
- Type
- journal article
- Language
- en
- Open access
- closed
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- Gordon, R. G. (1965). Molecular Motion in Infrared and Raman Spectra. The Journal of Chemical Physics. https://doi.org/10.1063/1.1696920
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Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
