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Dissociation and Isomerization of Vibrationally Excited Species. III
Abstract
The equations of Part I for the specific and over-all unimolecular reaction-rate constants are extended slightly by including centrifugal effects in a more detailed way and by making explicit allowance for possible reaction-path degeneracy (optically or geometrically isomeric paths). The expression for reaction-path degeneracy can be applied to other types of reactions in discussions of statistical factors in reaction rates.
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Citations
Cited by
Reaction-rate theory: fifty years after Kramers
Hänggi, P., Talkner, P., & Borkovec, M. (1990) · Reviews of Modern Physics · doi:10.1103/revmodphys.62.251 · Cited by 6,154
Statistical modeling of collision-induced dissociation thresholds
Rodgers, M. T., Ervin, K. M., & Armentrout, P. B. (1997) · The Journal of Chemical Physics · doi:10.1063/1.473494 · Cited by 468
Intramolecular vibrational redistribution: from high-resolution spectra to real-time dynamics
Makarov, A. A., Malinovsky, A. L., & Ryabov, E. A. (2012) · Physics-Uspekhi · doi:10.3367/ufne.0182.201210e.1047 · Cited by 370
Strange and Unconventional Isotope Effects in Ozone Formation
Gao, Y. Q., & Marcus, R. A. (2001) · Science · doi:10.1126/science.1058528 · Cited by 318
Self-citationClustering of water on hydrated protons in a supersonic free jet expansion
Searcy, J. Q., & Fenn, J. B. (1974) · The Journal of Chemical Physics · doi:10.1063/1.1681876 · Cited by 305
Metadata
- Authors
- Marcus, R. A.
- Venue
- The Journal of Chemical Physics
- Publisher
- AIP Publishing
- Published
- 1965-10-15
- Volume
- 43
- Issue
- 8
- Pages
- 2658-2661
- ISSN
- 0021-9606 (ISSN-L)
- 1089-7690
- OpenAlex
- W2035562399
- Cited by
- 190
- References
- 0
- FWCI
- 5.25
- Type
- journal article
- Language
- en
- Open access
- closed
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