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Self-Nucleation in the Sulfuric Acid-Water System
Abstract
Howard Reiss' ``Vector model'' was adapted to calculate the self-nucleation rate for the sulfuric acid-water system and similar systems. A numerical calculation was carried out for the typical case of 50% relative humidity at 25°C. It was concluded that rapid self-nucleation would take place at sulfuric acid partial pressures in the range 10-8-10-10 mm Hg. The considerable uncertainty is principally due to lack of data on the partial pressure of sulfuric acid above its aqueous solutions and on the dominant sulfuric acid-bearing species in humid atmospheres.
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Citations
Cited by
Parameterizations for sulfuric acid/water nucleation rates
Kulmala, M., Laaksonen, A., & Pirjola, L. (1998) · Journal of Geophysical Research: Atmospheres · doi:10.1029/97jd03718 · Cited by 419
Liu, L., Yu, F., Tu, K., Yang, Z., & Zhang, X. (2021) · Atmospheric Chemistry and Physics · doi:10.5194/acp-21-6221-2021 · Cited by 41
Metadata
- Authors
- Doyle, G. J.
- Venue
- The Journal of Chemical Physics
- Publisher
- AIP Publishing
- Published
- 1961-09-01
- Volume
- 35
- Issue
- 3
- Pages
- 795-799
- ISSN
- 0021-9606 (ISSN-L)
- 1089-7690
- OpenAlex
- W2015439200
- Cited by
- 282
- References
- 0
- FWCI
- 0.88
- Type
- journal article
- Language
- en
- Open access
- closed
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- Doyle, G. J. (1961). Self-Nucleation in the Sulfuric Acid-Water System. The Journal of Chemical Physics. https://doi.org/10.1063/1.1701218
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Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
