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Transition Metal Binding in DNA Solutions
Abstract
Paramagnetic ions in water shorten the spin-lattice relaxation time T1 of the water protons. The effectiveness with which the relaxation takes place depends not only on the ion concentration, but also on the environment of the paramagnetic ion. In some cases where the paramagnetic ion is bound to a large molecule such as DNA, it shortens the proton relaxation time to a greater extent than when it is in solution. By measuring T1 by a pulsed nuclear magnetic resonance method, we have studied the binding of transition metal ions to DNA. We have obtained estimates for the number of available binding sites as well as information on the type of site which the various ions are bound to.
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Cited by
Kinetic and Magnetic Resonance Studies of the Pyruvate Kinase Reaction
Mildvan, A. S., & Cohn, M. (1966) · Journal of Biological Chemistry · doi:10.1016/s0021-9258(18)96818-3 · Cited by 282
Fluoride inhibition of yeast enolase. 1. Formation of the ligand complexes
Maurer, P. J., & Nowak, T. (1981) · Biochemistry · doi:10.1021/bi00527a024 · Cited by 19
Metadata
- Authors
- Eisinger, J., Shulman, R. G., & Szymanski, B. M.
- Venue
- The Journal of Chemical Physics
- Publisher
- AIP Publishing
- Published
- 1962-04-01
- Volume
- 36
- Issue
- 7
- Pages
- 1721-1729
- ISSN
- 0021-9606 (ISSN-L)
- 1089-7690
- OpenAlex
- W1999540794
- Cited by
- 208
- References
- 0
- FWCI
- 7.19
- Type
- journal article
- Language
- en
- Open access
- closed
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- CoChat. (2026). Citation check: Transition Metal Binding in DNA Solutions. https://app.cochat.ai/papers/10.1063/1.1701258
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- Eisinger, J., Shulman, R. G., & Szymanski, B. M. (1962). Transition Metal Binding in DNA Solutions. The Journal of Chemical Physics. https://doi.org/10.1063/1.1701258
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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