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Lattice Constants and Thermal Expansivities of Silicon and of Calcium Fluoride between 6° and 322°K
Abstract
An x-ray back-reflection, rotating-camera technique has been used to obtain lattice constants and thermal expansivities of single-crystal silicon and calcium fluoride. Absolute expansivity was obtained over a broad range with an error less than 3 ppm. For silicon, this absolute method discriminates between earlier experiments showing some disagreement, and establishes with improved precision the temperature variation of the Grüneisen parameter γ in the region of particular interest (γ<0). For calcium fluoride the present x-ray measurements test a prediction of Ganesan and Srinivasan that γ should rise sharply below about 80°K. The prediction is not confirmed.
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Cited by
Milman, V., Winkler, B., White, J. A., Pickard, C. J., Payne, M. C., Akhmatskaya, E. V., & Nobes, R. H. (2000) · International Journal of Quantum Chemistry · doi:10.1002/(sici)1097-461x(2000)77:5<895::aid-qua10>3.0.co;2-c · Cited by 1,755
Thermal expansion of some diamondlike crystals
Slack, G. A., & Bartram, S. F. (1975) · Journal of Applied Physics · doi:10.1063/1.321373 · Cited by 767
Wilson, S. A. (2006) · American Mineralogist · doi:10.2138/am.2006.2058 · Cited by 172
The spin-lattice interaction for rare earth S-state ions
Oseroff, S. B., & Calvo, R. (1972) · Journal of Physics and Chemistry of Solids · doi:10.1016/s0022-3697(72)80301-9 · Cited by 26
The decomposition of konyaite: importance in CO2fixation in mine tailings
Mills, S. J., Wilson, S. A., Dipple, G. M., & Raudsepp, M. (2010) · Mineralogical Magazine · doi:10.1180/minmag.2010.074.5.903 · Cited by 19
Metadata
- Authors
- Batchelder, D. N., & Simmons, R. O.
- Venue
- The Journal of Chemical Physics
- Publisher
- AIP Publishing
- Published
- 1964-10-15
- Volume
- 41
- Issue
- 8
- Pages
- 2324-2329
- ISSN
- 0021-9606 (ISSN-L)
- 1089-7690
- OpenAlex
- W2002019385
- Cited by
- 237
- References
- 0
- FWCI
- 6.78
- Type
- journal article
- Language
- en
- Open access
- closed
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- Batchelder, D. N., & Simmons, R. O. (1964). Lattice Constants and Thermal Expansivities of Silicon and of Calcium Fluoride between 6° and 322°K. The Journal of Chemical Physics. https://doi.org/10.1063/1.1726266
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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