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Infrared Study of Adsorbed Molecules on Metal Surfaces by Reflection Techniques
Abstract
The problem of obtaining the infrared spectrum of a molecular monolayer adsorbed on a bulk metal is discussed. The intensity of an infrared absorption band in radiation reflected from the surface is calculated for (a) various optical constants of the adsorbed layer and the metal, (b) various thicknesses of the adsorbed layer, (c) various angles of incidence, and (d) both states of polarization of the incident radiation. The absorption factor for infrared radiation polarized parallel to the plane of incidence typically has a peak at an incident angle of about 88°, where the absorption is 5000 times greater than at normal incidence. The absorption of a thin layer by the reflection technique, at optimum conditions, is calculated to be about 25 times greater than by transmission through the unsupported film at normal incidence.
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Cited by
Ghosh, S. K., & Pal, T. (2007) · Chemical Reviews · doi:10.1021/cr0680282 · Cited by 2,782
Electric field standing wave artefacts in FTIR micro-spectroscopy of biological materials
Filik, J., Frogley, M. D., Pijanka, J. K., Wehbe, K., & Cinque, G. (2012) · The Analyst · doi:10.1039/c2an15995c · Cited by 122
Theory of Midinfrared Absorption Microspectroscopy: I. Homogeneous Samples
Davis, B. J., Carney, P. S., & Bhargava, R. (2010) · Analytical Chemistry · doi:10.1021/ac902067p · Cited by 115
Lee, J. (2017) · Vibrational Spectroscopy · doi:10.1016/j.vibspec.2017.03.007 · Cited by 20
Metadata
- Authors
- Greenler, R. G.
- Venue
- The Journal of Chemical Physics
- Publisher
- AIP Publishing
- Published
- 1966-01-01
- Volume
- 44
- Issue
- 1
- Pages
- 310-315
- ISSN
- 0021-9606 (ISSN-L)
- 1089-7690
- OpenAlex
- W2011764801
- Cited by
- 1,526
- References
- 0
- FWCI
- 2.41
- Type
- journal article
- Language
- en
- Open access
- closed
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- Greenler, R. G. (1966). Infrared Study of Adsorbed Molecules on Metal Surfaces by Reflection Techniques. The Journal of Chemical Physics. https://doi.org/10.1063/1.1726462
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