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Cited by 535

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Rate of Interconversion of Electronic and Vibrational Energy

Lin, Sheng Hsien·1966·The Journal of Chemical Physics

Abstract

Radiationless transitions are treated from the viewpoint of the nonstationary character of the Born—Oppenheimer approximation. It is shown that the theory explains the fast rates of internal conversion and highly variable rates of intersystem crossing, accounts for the temperature dependence and selection rules of radiationless transitions, and explains the deuterium effect and external heavy-atom effect on the radiationless transitions.

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Metadata

Authors
Lin, S. H.
Venue
The Journal of Chemical Physics
Published
1966-05-15
Volume
44
Issue
10
Pages
3759-3767
ISSN
  • 0021-9606 (ISSN-L)
  • 1089-7690
OpenAlex
W2050155948
Cited by
535
References
0
FWCI
11.79
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Rate of Interconversion of Electronic and Vibrational Energy. https://app.cochat.ai/papers/10.1063/1.1726531
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Lin, S. H. (1966). Rate of Interconversion of Electronic and Vibrational Energy. The Journal of Chemical Physics. https://doi.org/10.1063/1.1726531

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Bibliographic data: Semantic Scholar, OpenAlex, Crossref.

Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).

Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.