The DOI matches its Crossref record; 2 of the 2 references it cites were found in a registry or an index.
Oxygen Isotope Fractionation in the System Calcium Carbonate-Water
Abstract
The oxygen isotope exchange reaction between water and calcium carbonate has been studied over the temperature range 190°C to 750°C. Equilibrium constants for the reaction have been measured and fit the equation: lnK=2725T−2for all temperatures above 0°C. The implications to geological thermometry are discussed.
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Experimental studies on equilibrium fractionation in the CaCO3-H2O system indicate that dissolution-reprecipitation controls the rate of isotope exchange between finely dispersed calcium carbonate and aqueous solutions.
“Experimental studies on equilibrium fractionation in the CaCO₃-H2O system indicate that dissolution-reprecipitation controls the rate of isotope exchange between finely dispersed calcium carbonate and aqueous solutions (Clayton, 1959; Northrop and Clayton, 1966; O'Neil et al., 1969).”
From Oxygen isotope fractionation in carbonate and sulfate minerals. (1999) · cites this paper as Clayton, 1959
Clayton (1959) observed that the calcium carbonate in the high temperature experiments underwent recrystallization during polymorphic transition from aragonite to calcite and hence achieved new calcite-water isotope equilibrium under the hydrothermal conditions.
“Clayton (1959) observed that the calcium carbonate in the high temperature experiments underwent recrystallization during polymorphic transition from aragonite to calcite and hence achieved new calcite-water isotope equilibrium under the hydrothermal conditions.”
From Oxygen isotope fractionation in carbonate and sulfate minerals. (1999) · cites this paper as Clayton (1959)
Citations
Cites
Revised Carbonate-water isotopic temperature scale
EPSTEIN, S., BUCHSBAUM, R., LOWENSTAM, H. A., & UREY, H. C. (1953) · Geological Society of America Bulletin · doi:10.1130/0016-7606(1953)64[1315:rcits]2.0.co;2 · Cited by 2,271
Engel, A. E. J., Clayton, R. N., & Epstein, S. (1958) · The Journal of Geology · doi:10.1086/626524 · Cited by 85
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Flagged first, then by citations
Research works printed but not linked: 8
- 1950, Rev. Sci. Instr., 21, 724, 10.1063/1.1745698 · DOI
- 1958, J. Geol., 66, 352
- 1950, J. Chem. Phys., 18, 849, 10.1063/1.1747785 · DOI · Paper page
- 1953, Geochim. et Cosmochim. Acta, 4, 213, 10.1016/0016-7037(53)90051-9 · DOI
- 1949, Bull. Geol. Soc. Am., 60, 1727
- 1947, Rev. Sci. Instr., 18, 389, 10.1063/1.1740959 · DOI
- 1957, Geochim. et Cosmochim. Acta, 12, 133, 10.1016/0016-7037(57)90024-8 · DOI · Paper page
- 1947, J. Chem. Phys., 15, 261, 10.1063/1.1746492 · DOI · Paper page
Cited by
Sorted by citations
Oxygen Isotope Fractionation in Divalent Metal Carbonates
O'Neil, J. R., Clayton, R. N., & Mayeda, T. K. (1969) · The Journal of Chemical Physics · doi:10.1063/1.1671982 · Cited by 2,549
Self-citationOxygen isotope fractionation in carbonate and sulfate minerals.
Zheng, Y.-F. (1999) · GEOCHEMICAL JOURNAL · doi:10.2343/geochemj.33.109 · Cited by 489
“Experimental studies on equilibrium fraction ation in the CaCO3-H2O system indicate that dis solution-reprecipitation controls the rate of isotope exchange between finely dispersed calcium car bonate and aqueous solutions (Clayton, 1959; Northrop and Clayton, 1966; O'Neil et al., 1969).”
BackgroundMethodResultInfluentialSheppard, S. M. F., & Schwarcz, H. P. (1970) · Contributions to Mineralogy and Petrology · doi:10.1007/bf00373200 · Cited by 446
Oxygen-Isotope Fractionations in Systems Containing Dolomite
Northrop, D. A., & Clayton, R. N. (1966) · The Journal of Geology · doi:10.1086/627153 · Cited by 405
Self-citationFriedman, I. (1970) · Geochimica et Cosmochimica Acta · doi:10.1016/0016-7037(70)90043-8 · Cited by 168
Oxygen isotope geothermometers for metamorphic rocks
MATTHEWS, A. (1994) · Journal of Metamorphic Geology · doi:10.1111/j.1525-1314.1994.tb00017.x · Cited by 126
Metadata
- Authors
- Clayton, R. N.
- Affiliations
- Pennsylvania State University (US)
- Corresponding author
- Clayton, Robert N.
- Venue
- The Journal of Chemical Physics
- Publisher
- AIP Publishing
- Published
- 1959-05-01
- Volume
- 30
- Issue
- 5
- Pages
- 1246-1250
- ISSN
- 0021-9606 (ISSN-L)
- 1089-7690
- OpenAlex
- W2007205102
- Cited by
- 45
- References
- 2
- Citations by year
- 2026: 1 · 2024: 1 · 2021: 2 · 2020: 1 · 2018: 1 · 2015: 2 · 2013: 2
- FWCI
- 1.95
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- The Journal of Chemical Physics (publishedVersion)
- Topics
- Physical Sciences › Earth and Planetary Sciences › Geochemistry and Petrology › Geological and Geochemical Analysis
- Physical Sciences › Earth and Planetary Sciences › Geochemistry and Petrology › Groundwater and Isotope Geochemistry
- Physical Sciences › Earth and Planetary Sciences › Geochemistry and Petrology › Geochemistry and Elemental Analysis
- Keywords
- oxygen isotope fractionation, calcium carbonate, water, isotope exchange, equilibrium constants, temperature dependence
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