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Studies in Molecular Dynamics. II. Behavior of a Small Number of Elastic Spheres
Abstract
The equation of state and the collision rate for systems ranging in size from four to 500 particles are described. The dependence of the results on the number of particles is qualitatively discussed and in this way insight is gained as to what is required of more accurate analytical theories. By comparing the results to various analytical theories now available their region of validity is established. The number of particles necessary at various densities to obtain a quantitative description of the equilibrium properties is delineated. Whether a first-order phase transition exists for hard spheres remains open until larger systems are investigated.
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Cited by
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Allen, M. P., & Tildesley, D. J. (2017) · doi:10.1093/oso/9780198803195.001.0001 · Cited by 20,945
Role of repulsive forces in determining the equilibrium structure of simple liquids
Weeks, J. D., Chandler, D., & Andersen, H. C. (1971) · The Journal of Chemical Physics · doi:10.1063/1.1674820 · Cited by 5,207
Efficient estimation of free energy differences from Monte Carlo data
Bennett, C. H. (1976) · Journal of Computational Physics · doi:10.1016/0021-9991(76)90078-4 · Cited by 2,755
What is "liquid"? Understanding the states of matter
Barker, J. A., & Henderson, D. (1976) · Reviews of Modern Physics · doi:10.1103/revmodphys.48.587 · Cited by 2,104
Percus–Yevick Equation for Hard Spheres with Surface Adhesion
Baxter, R. J. (1968) · The Journal of Chemical Physics · doi:10.1063/1.1670482 · Cited by 1,208
Metadata
- Authors
- Alder, B. J., & Wainwright, T. E.
- Venue
- The Journal of Chemical Physics
- Publisher
- AIP Publishing
- Published
- 1960-11-01
- Volume
- 33
- Issue
- 5
- Pages
- 1439-1451
- ISSN
- 0021-9606 (ISSN-L)
- 1089-7690
- OpenAlex
- W2092691863
- Cited by
- 816
- References
- 0
- FWCI
- 8.90
- Type
- journal article
- Language
- en
- Open access
- closed
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- Alder, B. J., & Wainwright, T. E. (1960). Studies in Molecular Dynamics. II. Behavior of a Small Number of Elastic Spheres. The Journal of Chemical Physics. https://doi.org/10.1063/1.1731425
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