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Cited by 528

The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.

Optical Rotatory Dispersion of Helical Polymers

Moffitt, William·1956·The Journal of Chemical Physics

Abstract

It is shown that for every transition in its individual residues, a helix has two transitions whose moments are respectively parallel and perpendicular to the screw axis. The largest contributions to the rotational strengths of these bands are equal and opposite in the two cases. As a result, their net effect on the optical activity contains a term proportional to the interval between the two upper states. This term shows abnormal dispersion and its magnitude and sign are more easily interpreted than any other component of the rotatory power.

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Metadata

Authors
Moffitt, W.
Venue
The Journal of Chemical Physics
Published
1956-09-01
Volume
25
Issue
3
Pages
467-478
ISSN
  • 0021-9606 (ISSN-L)
  • 1089-7690
OpenAlex
W2083219962
Cited by
528
References
1
FWCI
8.43
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Optical Rotatory Dispersion of Helical Polymers. https://app.cochat.ai/papers/10.1063/1.1742946
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Moffitt, W. (1956). Optical Rotatory Dispersion of Helical Polymers. The Journal of Chemical Physics. https://doi.org/10.1063/1.1742946

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Bibliographic data: Semantic Scholar, OpenAlex, Crossref.

Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).

Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.