The DOI matches its Crossref record; 3 of the 3 references it cites were found in a registry or an index.
Reactions of Gaseous Molecule Ions with Gaseous Molecules. V. Theory
Abstract
Ion-molecule reactions of the sort observed as secondary reactions in mass spectrometers have been treated by the methods of the modern kinetic theory; that is, the rate of reaction is expressed in terms of the velocity distribution functions of the reactants and the cross section for the reaction. The cross section, which is calculated by means of the properties of the classical collision orbits, is found to have an inverse square root dependence on energy. The ion distribution function, which is far from Maxwellian, is found by means of an explicit solution of the Boltzmann equation. A simple relation is given which relates the mass spectrometric data to the specific rate of the same reaction under thermal conditions. For the simpler molecules, this rate may be calculated completely a priori, with excellent agreement with experiment.
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Citations
Cites
Molecular Theory of Gases and Liquids
Hirschfelder, J. O., Curtiss, C. F., & Bird, R. B. (1955) · Physics Today · doi:10.1063/1.3061949 · Cited by 11,418
Eyring, H., Hirschfelder, J. O., & Taylor, H. S. (1936) · The Journal of Chemical Physics · doi:10.1063/1.1749888 · Cited by 241
Reactions of Gaseous Molecule Ions with Gaseous Molecules. IV. Experimental Method and Results
Stevenson, D. P., & Schissler, D. O. (1958) · The Journal of Chemical Physics · doi:10.1063/1.1744476 · Cited by 194
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Cited by
Ludlow, A. D., Boyd, M. M., Ye, J., Peik, E., & Schmidt, P. O. (2015) · Reviews of Modern Physics · doi:10.1103/revmodphys.87.637 · Cited by 2,385
Current Status of Transition-State Theory
Truhlar, D. G., Garrett, B. C., & Klippenstein, S. J. (1996) · The Journal of Physical Chemistry · doi:10.1021/jp953748q · Cited by 2,279
Su, T., & Bowers, M. T. (1973) · International Journal of Mass Spectrometry and Ion Physics · doi:10.1016/0020-7381(73)80104-4 · Cited by 526
Su, T., & Bowers, M. T. (1973) · The Journal of Chemical Physics · doi:10.1063/1.1679615 · Cited by 428
Ion/Ion Reactions in the Gas Phase: Proton Transfer Reactions Involving Multiply-Charged Proteins
Stephenson, J. L., & McLuckey, S. A. (1996) · Journal of the American Chemical Society · doi:10.1021/ja9611755 · Cited by 215
Metadata
- Authors
- Gioumousis, G., & Stevenson, D. P.
- Venue
- The Journal of Chemical Physics
- Publisher
- AIP Publishing
- Published
- 1958-08-01
- Volume
- 29
- Issue
- 2
- Pages
- 294-299
- ISSN
- 0021-9606 (ISSN-L)
- 1089-7690
- OpenAlex
- W2019737727
- Cited by
- 1,375
- References
- 3
- FWCI
- 4.78
- Type
- journal article
- Language
- en
- Open access
- closed
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