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On the Theory of Strong Electrolyte Solutions
Abstract
The nature of the approximations involved in the derivation of the Poisson-Boltzmann equation of the Debye-Hückel theory is investigated in detail from the standpoint of classical statistical mechanics. The validity of the initial Debye approximation, under the restrictions originally imposed upon it, is confirmed. Deviations arising from fluctuation terms and van der Waals forces are roughly estimated. An alternative to the Bjerrum method for the treatment of ions of small size and high valence is outlined.
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Cited by
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Beck, T. L. (2000) · Reviews of Modern Physics · doi:10.1103/revmodphys.72.1041 · Cited by 473
Vibrational Spectroscopic Map, Vibrational Spectroscopy, and Intermolecular Interaction
Baiz, C. R., Błasiak, B., Bredenbeck, J., Cho, M., Choi, J.-H., Corcelli, S. A., Dijkstra, A. G., Feng, C.-J., Garrett-Roe, S., Ge, N.-H., et al. (2020) · Chemical Reviews · doi:10.1021/acs.chemrev.9b00813 · Cited by 412
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Metadata
- Authors
- Kirkwood, J. G.
- Venue
- The Journal of Chemical Physics
- Publisher
- AIP Publishing
- Published
- 1934-11-01
- Volume
- 2
- Issue
- 11
- Pages
- 767-781
- ISSN
- 0021-9606 (ISSN-L)
- 1089-7690
- OpenAlex
- W2001711568
- Cited by
- 207
- References
- 0
- FWCI
- 3.08
- Type
- journal article
- Language
- en
- Open access
- closed
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- Kirkwood, J. G. (1934). On the Theory of Strong Electrolyte Solutions. The Journal of Chemical Physics. https://doi.org/10.1063/1.1749393
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
