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Cited by 41Chemical Reactions and IsotopesHydrogen Storage and MaterialsCatalysis and Oxidation Reactions

The DOI matches its Crossref record.

The Inter-Relations of Hydrogen and Deuterium Molecules

Gould, Austin J., Bleakney, Walker, Taylor, Hugh S.·1934·The Journal of Chemical Physics
DOI 10.1063/1.1749490
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Abstract

It has been shown that neither stopcock grease nor water in a Pyrex or soft-glass vessel affect the concentration of hydrogen-deuterium mixtures. Diffusion through palladium gives a concentration of the isotopes which is about that to be expected from an atomic diffusion process. Desorption from charcoal at liquid air temperatures gives the concentration effect to be expected from a diffusion as molecules. Mercury, Pyrex and soft-glass surfaces at room temperature and charcoal at liquid air temperatures do not promote the reaction between hydrogen and deuterium. Chromium oxide and nickel-kieselguhr surfaces promote the reaction between hydrogen and deuterium in the temperature range between — 190° and 110°C. A palladium surface catalyzes the reaction at 270°C. Experimental values have been obtained for the equilibrium constant of the reaction between hydrogen and deuterium from the temperature of liquid air upwards, in accord with theoretical calculations by Urey and Rittenberg based on statistical mechanics.

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  • Separation-oriented adsorption studies of hydrogen isotopes on activated carbons, silicas, and zeolites have been reported since the 1930s.

    “Separation-oriented adsorption studies of hydrogen isotopes on activated carbons, silicas, and zeolites have been reported since the 1930s by several authors.398−404”

    From Zeolites in Adsorption Processes: State of the Art and Future Prospects (2022) · cites this paper as [398]

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No references could be resolved yet.

Research works printed but not linked: 25

  1. 1932, Phys. Rev., 40, 496, 10.1103/PhysRev.40.496 · DOI
  2. 1932, Phys. Rev., 41, 32, 10.1103/PhysRev.41.32 · DOI
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Metadata

Authors
Gould, A. J., Bleakney, W., & Taylor, H. S.
Affiliations
Princeton University (US)
ORCID
Taylor, Hugh S.
Venue
The Journal of Chemical Physics
Publisher
AIP Publishing
Published
1934-07-01
Volume
2
Issue
7
Pages
362-373
ISSN
  • 0021-9606 (ISSN-L)
  • 1089-7690
DOI
10.1063/1.1749490
OpenAlex
W1998719762
Cited by
41
References
0
Citations by year
2024: 1 · 2022: 2 · 2018: 1 · 2017: 1 · 2015: 1 · 2013: 1
FWCI
1.69
Type
journal article
Language
en
Open access
closed
Locations
The Journal of Chemical Physics (publishedVersion)
Topics
  • Life Sciences › Pharmacology, Toxicology and Pharmaceutics › Pharmaceutical Science › Chemical Reactions and Isotopes
  • Physical Sciences › Materials Science › Materials Chemistry › Hydrogen Storage and Materials
  • Physical Sciences › Chemical Engineering › Catalysis › Catalysis and Oxidation Reactions
Keywords
hydrogen-deuterium exchange, isotope exchange, palladium catalysis, molecular diffusion, Mercury surface, liquid air temperature, equilibrium constants, statistical mechanics, surface catalysis

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