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The Diamagnetic Anisotropy of Aromatic Molecules

Pauling, Linus·1936·The Journal of Chemical Physics
DOI 10.1063/1.1749766
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Abstract

Values of the diamagnetic anisotropy of benzene and other aromatic hydrocarbon molecules are calculated on the basis of the assumption that the pz electrons (one per aromatic carbon atom) are free to move from carbon atom to adjacent carbon atom under the influence of the impressed fields. When combined with the assumed values for the contributions of the other electrons (-2.0×10-6 for hydrogen, -4.5×10-6 for aromatic carbon, -6.0×10-6 for aliphatic carbon) these lead to principal diamagnetic susceptibilities of molecules in approximate agreement with the available experimental data. The diamagnetic anisotropy of graphite is also discussed.

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Metadata

Authors
Pauling, L.
Venue
The Journal of Chemical Physics
Publisher
AIP Publishing
Published
1936-10-01
Volume
4
Issue
10
Pages
673-677
ISSN
  • 0021-9606 (ISSN-L)
  • 1089-7690
DOI
10.1063/1.1749766
OpenAlex
W2028737713
Cited by
731
References
0
FWCI
2.98
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: The Diamagnetic Anisotropy of Aromatic Molecules. https://app.cochat.ai/papers/10.1063/1.1749766
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Pauling, L. (1936). The Diamagnetic Anisotropy of Aromatic Molecules. The Journal of Chemical Physics. https://doi.org/10.1063/1.1749766

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Bibliographic data: Semantic Scholar, OpenAlex, Crossref.

Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).

Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.