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The origin of slow electron recombination processes in dye-sensitized solar cells with alumina barrier coatings

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Fabregat-Santiago, Francisco, García-Cañadas, Jorge, Palomares, Emilio, Clifford, John N., Haque, Saif A., Durrant, James R., Garcia-Belmonte, Germà, Bisquert, Juan·2004·Journal of Applied Physics

Abstract

We investigate the effect of a thin alumina coating of nanocrystalline TiO2 films on recombination dynamics of dye-sensitized solar cells. Both coated and uncoated cells were measured by a combination of techniques: transient absorption spectroscopy, electrochemical impedance spectroscopy, and open-circuit voltage decay. It is found that the alumina barrier reduces the recombination of photoinjected electrons to both dye cations and the oxidized redox couple. It is proposed that this observed retardation can be attributed primarily to two effects: almost complete passivation of surface trap states in TiO2 that are able to inject electrons to acceptor species, and slowing down by a factor of 3–4 the rate of interfacial charge transfer from conduction-band states.

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Metadata

Authors
Fabregat-Santiago, F., García-Cañadas, J., Palomares, E., Clifford, J. N., Haque, S. A., Durrant, J. R., Garcia-Belmonte, G., & Bisquert, J.
Venue
Journal of Applied Physics
Published
2004-12-01
Volume
96
Issue
11
Pages
6903-6907
ISSN
  • 0021-8979 (ISSN-L)
  • 1089-7550
OpenAlex
W2023360332
Cited by
193
References
0
FWCI
8.08
Type
journal article
Language
en
Open access
bronze

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CoChat. (2026). Citation check: The origin of slow electron recombination processes in dye-sensitized solar cells with alumina barrier coatings. https://app.cochat.ai/papers/10.1063/1.1812588
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Fabregat-Santiago, F., García-Cañadas, J., Palomares, E., Clifford, J. N., Haque, S. A., Durrant, J. R., Garcia-Belmonte, G., & Bisquert, J. (2004). The origin of slow electron recombination processes in dye-sensitized solar cells with alumina barrier coatings. Journal of Applied Physics. https://doi.org/10.1063/1.1812588

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