The DOI matches its Crossref record; 13 of the 13 references it cites were found in a registry or an index.
Thermodynamic and Conformational Properties of Polystyrene. II. Intrinsic Viscosity Studies on Dilute Solutions of Linear Polystyrenes
Abstract
The results of an extensive study of the intrinsic viscosity [η] of a series of linear, homogeneous (anionically prepared) polystyrenes (1.9<10−4M<440) over a wide temperature interval (10°<T<110°C) in decalin and toluene are described. The data are discussed in relation to the interaction parameter z=B0(〈s2〉0/M)−3/2(1−Θ/T)M1/2 in which the constants B0, Θ, and 〈s2〉0/M have been determined from thermodynamic studies reported in Part I of this series. It is found that [η]/[η]0 is not a single-valued function of z except for M>∼106. Above this molecular weight the dependence of [η]/[η]0 on z is satisfactorily predicted by recent calculations of Fixman; [η]/[η]0 is not linear in z contrary to other recent suggestions. The failure of the data on lower molecular weight polymers to be a single-valued function of z is discussed in terms of partial draining effects.
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Citations
Cites
Zimm, B. H. (1956) · The Journal of Chemical Physics · doi:10.1063/1.1742462 · Cited by 2,567
The Intrinsic Viscosities and Diffusion Constants of Flexible Macromolecules in Solution
Kirkwood, J. G., & Riseman, J. (1948) · The Journal of Chemical Physics · doi:10.1063/1.1746947 · Cited by 1,394
Berry, G. C. (1966) · The Journal of Chemical Physics · doi:10.1063/1.1726673 · Cited by 741
Self-citationIntrinsic viscosities and unperturbed dimensions of long chain molecules
Kurata, M., & Stockmayer, W. H. (1963) · Advances in Polymer Science · doi:10.1007/bfb0050490 · Cited by 726
On the estimation of unperturbed dimensions from intrinsic viscositiesxcin
Stockmayer, W. H., & Fixman, M. (1963) · Journal of Polymer Science Part C: Polymer Symposia · doi:10.1002/polc.5070010109 · Cited by 591
SIMPLIFIED ROTATING CYLINDER VISCOMETER FOR DNA
Zimm, B. H., & Crothers, D. M. (1962) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.48.6.905 · Cited by 273
Intrinsic Viscosity-Molecular Weight Relationships for Polyisobutylene.
Fox, T. G., & Flory, P. J. (1949) · The Journal of Physical and Colloid Chemistry · doi:10.1021/j150467a001 · Cited by 221
Effect of Volume Exclusion on the Dimensions of Polymer Chains
Flory, P. J., & Fisk, S. (1966) · The Journal of Chemical Physics · doi:10.1063/1.1727029 · Cited by 145
Second and Fourth Moments of Chain Molecules
Flory, P. J., & Jernigan, R. L. (1965) · The Journal of Chemical Physics · doi:10.1063/1.1695753 · Cited by 131
Intrinsic Viscosity-Molecular Weight Relationship for Fractions of Linear Polyethylene1
Chiang, R. (1965) · The Journal of Physical Chemistry · doi:10.1021/j100889a034 · Cited by 110
Cited by
Valence and patterning of aromatic residues determine the phase behavior of prion-like domains
Martin, E. W., Holehouse, A. S., Peran, I., Farag, M., Incicco, J. J., Bremer, A., Grace, C. R., Soranno, A., Pappu, R. V., & Mittag, T. (2020) · Science · doi:10.1126/science.aaw8653 · Cited by 1,147
Metadata
- Authors
- Berry, G. C.
- Venue
- The Journal of Chemical Physics
- Publisher
- AIP Publishing
- Published
- 1967-02-15
- Volume
- 46
- Issue
- 4
- Pages
- 1338-1352
- ISSN
- 0021-9606 (ISSN-L)
- 1089-7690
- OpenAlex
- W2057944506
- Cited by
- 261
- References
- 13
- FWCI
- 17.31
- Type
- journal article
- Language
- en
- Open access
- closed
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- Berry, G. C. (1967). Thermodynamic and Conformational Properties of Polystyrene. II. Intrinsic Viscosity Studies on Dilute Solutions of Linear Polystyrenes. The Journal of Chemical Physics. https://doi.org/10.1063/1.1840854
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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