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Polarizability of the Hydrogen Molecule
Abstract
A variation perturbation method has been employed to calculate the static dipole polarizabilities of the hydrogen molecule. The wavefunction was represented by an expansion in elliptic coordinates including the interelectronic distance. A 54-term expansion was used for the zero-order wavefunction and 34 terms for the first-order corrections. The polarizabilities computed for several values of the internuclear distance (0.4≤R≤4.0) were averaged for various vibrational and rotational states of H2, HD, and D2. The results are in a satisfactory agreement with the experimental values.
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Citations
Cited by
The solid molecular hydrogens in the condensed phase: Fundamentals and static properties
Silvera, I. F. (1980) · Reviews of Modern Physics · doi:10.1103/revmodphys.52.393 · Cited by 1,207
The isotropic intermolecular potential for H2 and D2 in the solid and gas phases
Silvera, I. F., & Goldman, V. V. (1978) · The Journal of Chemical Physics · doi:10.1063/1.437103 · Cited by 601
Bubin, S., Pavanello, M., Tung, W.-C., Sharkey, K. L., & Adamowicz, L. (2013) · Chemical Reviews · doi:10.1021/cr200419d · Cited by 175
Metadata
- Authors
- Kol/os, W., & Wolniewicz, L.
- Venue
- The Journal of Chemical Physics
- Publisher
- AIP Publishing
- Published
- 1967-02-15
- Volume
- 46
- Issue
- 4
- Pages
- 1426-1432
- ISSN
- 0021-9606 (ISSN-L)
- 1089-7690
- OpenAlex
- W1483196670
- Cited by
- 515
- References
- 0
- FWCI
- 12.27
- Type
- journal article
- Language
- en
- Open access
- closed
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- Kol/os, W., & Wolniewicz, L. (1967). Polarizability of the Hydrogen Molecule. The Journal of Chemical Physics. https://doi.org/10.1063/1.1840870
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