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Efficiency improvement in solid-state-dye-sensitized photovoltaics with an amphiphilic Ruthenium-dye
Open accessAbstract
We report a solid-state-dye-sensitized solar cell with an efficiency of 4% over the standard air mass 1.5 spectrum (100mW∕cm2). This was made possible by using an amphiphilic dye with hydrophobic spacers. We attribute the performance to the self-assembly of the dye to a dense layer on the TiO2 surface with its carboxylate groups as anchors and with its hydrophobic isolating chains as blocking layer between hole conductor and TiO2. In addition we studied the dependence of the thickness of the nanoporous TiO2 layer and the device performance. These results show the high potential for solid-state-dye-sensitized solar cells to compete with amorphous silicon cells as low-cost alternative.
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Cited by
Park, N.-G. (2013) · The Journal of Physical Chemistry Letters · doi:10.1021/jz400892a · Cited by 1,382
A Review of Perovskites Solar Cell Stability
Wang, R., Mujahid, M., Duan, Y., Wang, Z., Xue, J., & Yang, Y. (2019) · Advanced Functional Materials · doi:10.1002/adfm.201808843 · Cited by 1,310
Dye-Sensitized Solar Cells: Fundamentals and Current Status
Sharma, K., Sharma, V., & Sharma, S. S. (2018) · Nanoscale Research Letters · doi:10.1186/s11671-018-2760-6 · Cited by 1,084
Organolead Halide Perovskite: New Horizons in Solar Cell Research
Kim, H.-S., Im, S. H., & Park, N.-G. (2014) · The Journal of Physical Chemistry C · doi:10.1021/jp409025w · Cited by 722
Advances in Liquid‐Electrolyte and Solid‐State Dye‐Sensitized Solar Cells
Snaith, H. J., & Schmidt‐Mende, L. (2007) · Advanced Materials · doi:10.1002/adma.200602903 · Cited by 616
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Metadata
- Authors
- Schmidt-Mende, L., Zakeeruddin, S. M., & Grätzel, M.
- Venue
- Applied Physics Letters
- Publisher
- AIP Publishing
- Published
- 2004-12-28
- Volume
- 86
- Issue
- 1
- ISSN
- 0003-6951 (ISSN-L)
- 1077-3118
- OpenAlex
- W2043349432
- Cited by
- 215
- References
- 0
- FWCI
- 14.34
- Type
- journal article
- Language
- en
- Open access
- green
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- Schmidt-Mende, L., Zakeeruddin, S. M., & Grätzel, M. (2005). Efficiency improvement in solid-state-dye-sensitized photovoltaics with an amphiphilic Ruthenium-dye. Applied Physics Letters. https://doi.org/10.1063/1.1844032
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