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Inverted bulk-heterojunction organic photovoltaic device using a solution-derived ZnO underlayer
Abstract
Inverted organic photovoltaic devices based on a blend of poly(3-hexylthiophene) and a fullerene have been developed by inserting a solution-processed ZnO interlayer between the indium tin oxide (ITO) electrode and the active layer using Ag as a hole-collecting back contact. Efficient electron extraction through the ZnO and hole extraction through the Ag, with minimal loss in open-circuit potential, is observed with a certified power conversion efficiency of 2.58%. The inverted architecture removes the need for the use of poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) as an ITO modifier and for the use of a low-work-function metal as the back contact in the device.
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Cited by
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You, J., Dou, L., Yoshimura, K., Kato, T., Ohya, K., Moriarty, T., Emery, K., Chen, C.-C., Gao, J., Li, G., et al. (2013) · Nature Communications · doi:10.1038/ncomms2411 · Cited by 2,778
Sun, Y., Seo, J. H., Takacs, C. J., Seifter, J., & Heeger, A. J. (2011) · Advanced Materials · doi:10.1002/adma.201004301 · Cited by 1,545
Dang, M. T., Hirsch, L., Wantz, G., & Wuest, J. D. (2013) · Chemical Reviews · doi:10.1021/cr300005u · Cited by 587
Polymer Solar Cells That Use Self‐Assembled‐Monolayer‐ Modified ZnO/Metals as Cathodes
Yip, H., Hau, S. K., Baek, N. S., Ma, H., & Jen, A. K. ‐. (2008) · Advanced Materials · doi:10.1002/adma.200703050 · Cited by 561
Highly efficient inverted polymer solar cell by low temperature annealing of Cs2CO3 interlayer
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Metadata
- Authors
- White, M. S., Olson, D. C., Shaheen, S. E., Kopidakis, N., & Ginley, D. S.
- Venue
- Applied Physics Letters
- Publisher
- AIP Publishing
- Published
- 2006-10-02
- Volume
- 89
- Issue
- 14
- ISSN
- 0003-6951 (ISSN-L)
- 1077-3118
- OpenAlex
- W1970156621
- Cited by
- 813
- References
- 0
- FWCI
- 22.60
- Type
- journal article
- Language
- en
- Open access
- closed
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- White, M. S., Olson, D. C., Shaheen, S. E., Kopidakis, N., & Ginley, D. S. (2006). Inverted bulk-heterojunction organic photovoltaic device using a solution-derived ZnO underlayer. Applied Physics Letters. https://doi.org/10.1063/1.2359579
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