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Lithium superionic conduction in lithium borohydride accompanied by structural transition
Open accessAbstract
The electrical conductivity of lithium borohydride (LiBH4) measured by the ac complex impedance method jumped by three orders of magnitude due to structural transition from orthorhombic to hexagonal at approximately 390K. The hexagonal phase exhibited a high electrical conductivity of the order of 10−3Scm−1. Furthermore, the conductivity calculated from the Nernst-Einstein equation using the correlation time obtained from Li7 nuclear magnetic resonance was in good agreement with the measured electrical conductivity. It was concluded that the electrical conductivity in the hexagonal phase is due to the Li superionic conduction.
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Citations
Cited by
Gao, Z., Sun, H., Fu, L., Ye, F., Zhang, Y., Luo, W., & Huang, Y. (2018) · Advanced Materials · doi:10.1002/adma.201705702 · Cited by 1,300
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The renaissance of hydrides as energy materials
Mohtadi, R., & Orimo, S.-I. (2016) · Nature Reviews Materials · doi:10.1038/natrevmats.2016.91 · Cited by 508
Self-citationMetal borohydrides and derivatives – synthesis, structure and properties
Paskevicius, M., Jepsen, L. H., Schouwink, P., Černý, R., Ravnsbæk, D. B., Filinchuk, Y., Dornheim, M., Besenbacher, F., & Jensen, T. R. (2017) · Chemical Society Reviews · doi:10.1039/c6cs00705h · Cited by 406
Mobile Ions in Composite Solids
Zou, Z., Li, Y., Lu, Z., Wang, D., Cui, Y., Guo, B., Li, Y., Liang, X., Feng, J., Li, H., et al. (2020) · Chemical Reviews · doi:10.1021/acs.chemrev.9b00760 · Cited by 348
Metadata
- Authors
- Matsuo, M., Nakamori, Y., Orimo, S.-I., Maekawa, H., & Takamura, H.
- Venue
- Applied Physics Letters
- Publisher
- AIP Publishing
- Published
- 2007-11-26
- Volume
- 91
- Issue
- 22
- Pages
- 224103-1-224103-3
- ISSN
- 0003-6951 (ISSN-L)
- 1077-3118
- OpenAlex
- W2085464244
- Cited by
- 479
- References
- 0
- FWCI
- 10.71
- Type
- journal article
- Language
- en
- Open access
- green
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- Matsuo, M., Nakamori, Y., Orimo, S.-I., Maekawa, H., & Takamura, H. (2007). Lithium superionic conduction in lithium borohydride accompanied by structural transition. Applied Physics Letters. https://doi.org/10.1063/1.2817934
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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