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Crystal structure and multiferroic properties of Gd-substituted BiFeO3
Abstract
Room-temperature crystal structure, local ferroelectric, and magnetic properties of the Bi1−xGdxFeO3 (x=0.1,0.2,0.3) polycrystalline samples have been investigated by x-ray diffraction, piezoresponse force microscopy, and magnetometry techniques. Performed measurements have revealed a sequence of the composition-driven structural phase transitions R3c→Pn21a (occurs at x∼0.1) and Pn21a→Pnma (takes place within the concentrational range of 0.2<x<0.3). The latter structural transformation is attributed to the substitution-induced suppression of the polar displacements. Gd substitution has been shown to effectively induce the appearance of the spontaneous magnetization, thus indicating a promising way for improving multiferroic properties of antiferromagnetic BiFeO3.
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Citations
Cites
Anisotropic Superexchange Interaction and Weak Ferromagnetism
Moriya, T. (1960) · Physical Review · doi:10.1103/physrev.120.91 · Cited by 7,234
Cited by
Enhanced Photocatalytic Activity and Ferromagnetism in Gd Doped BiFeO3 Nanoparticles
Guo, R., Fang, L., Dong, W., Zheng, F., & Shen, M. (2010) · The Journal of Physical Chemistry C · doi:10.1021/jp104660a · Cited by 406
Metadata
- Authors
- Khomchenko, V. A., Kiselev, D. A., Bdikin, I. K., Shvartsman, V. V., Borisov, P., Kleemann, W., Vieira, J. M., & Kholkin, A. L.
- Venue
- Applied Physics Letters
- Publisher
- AIP Publishing
- Published
- 2008-12-29
- Volume
- 93
- Issue
- 26
- ISSN
- 0003-6951 (ISSN-L)
- 1077-3118
- OpenAlex
- W1972887342
- Cited by
- 186
- References
- 1
- FWCI
- 4.05
- Type
- journal article
- Language
- en
- Open access
- closed
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- Khomchenko, V. A., Kiselev, D. A., Bdikin, I. K., Shvartsman, V. V., Borisov, P., Kleemann, W., Vieira, J. M., & Kholkin, A. L. (2008). Crystal structure and multiferroic properties of Gd-substituted BiFeO3. Applied Physics Letters. https://doi.org/10.1063/1.3058708
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