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Cited by 315

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Isotope effects in liquid water by infrared spectroscopy. III. H2O and D2O spectra from 6000tocm−1

Max, Jean-Joseph, Chapados, Camille·2009·The Journal of Chemical Physics

Abstract

The infrared spectra (IR) of pure liquid light (H2O) and heavy (D2O) water were obtained with attenuated total reflection (ATR) and transmission measurements in the mid-IR and far-IR. With these and with other values obtained from the literature, the real (n) and imaginary parts (k) of the refractive index were meticulously derived in the complete IR region from 6000to0cm−1. The reliability of the results resides in the critical comparison of our experimental data with that obtained from other laboratories and between calculated and experimental spectra, obtained by ATR and transmission techniques. The new optical properties (n and k) can now be used as standards for liquid H2O and D2O. To these we have added the water (H and D) absorption coefficients (K) that are derived from the k values. These can be used as references for spectra obtained by transmission with an absorbance intensity scale because they are almost the same.

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Metadata

Authors
Max, J.-J., & Chapados, C.
Venue
The Journal of Chemical Physics
Published
2009-11-11
Volume
131
Issue
18
Pages
184505-184505
ISSN
  • 0021-9606 (ISSN-L)
  • 1089-7690
OpenAlex
W1528352005
Cited by
315
References
3
FWCI
5.39
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Isotope effects in liquid water by infrared spectroscopy. III. H2O and D2O spectra from 6000tocm−1. https://app.cochat.ai/papers/10.1063/1.3258646
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Max, J.-J., & Chapados, C. (2009). Isotope effects in liquid water by infrared spectroscopy. III. H2O and D2O spectra from 6000tocm−1. The Journal of Chemical Physics. https://doi.org/10.1063/1.3258646

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